1 | Reading file /home/cljanss/mpqc-verify-tmp/mpqc.install.1/share/mpqc/2.2.3-snapshot/atominfo.kv.
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2 |
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3 | MPQC: Massively Parallel Quantum Chemistry
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4 | Version 2.2.3-snapshot
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5 |
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6 | Machine: x86_64-unknown-linux-gnu
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7 | User: cljanss@quad
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8 | Start Time: Thu Dec 16 12:10:45 2004
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9 |
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10 | Using ProcMessageGrp for message passing (number of nodes = 1).
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11 | Using PthreadThreadGrp for threading (number of threads = 4).
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12 | Using ProcMemoryGrp for distributed shared memory.
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13 | Total number of processors = 4
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14 |
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15 | Using IntegralV3 by default for molecular integrals evaluation
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16 |
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17 | Reading file /home/cljanss/mpqc-verify-tmp/mpqc.install.1/share/mpqc/2.2.3-snapshot/atominfo.kv.
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18 | Molecule: setting point group to c2v
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19 | Reading file /home/cljanss/mpqc-verify-tmp/mpqc.install.1/share/mpqc/2.2.3-snapshot/basis/cc-pvdz.kv.
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20 | Reading file /home/cljanss/mpqc-verify-tmp/mpqc.install.1/share/mpqc/2.2.3-snapshot/basis/sto-3g.kv.
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21 |
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22 | CLSCF::init: total charge = 0
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23 |
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24 | Starting from core Hamiltonian guess
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25 |
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26 | Using symmetric orthogonalization.
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27 | n(basis): 4 0 1 2
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28 | Maximum orthogonalization residual = 1.94039
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29 | Minimum orthogonalization residual = 0.335627
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30 | docc = [ 3 0 1 1 ]
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31 | nbasis = 7
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32 |
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33 | CLSCF::init: total charge = 0
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34 |
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35 | Projecting guess wavefunction into the present basis set
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36 |
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37 | SCF::compute: energy accuracy = 1.0000000e-06
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38 |
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39 | integral intermediate storage = 68472 bytes
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40 | integral cache = 31931080 bytes
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41 | nuclear repulsion energy = 9.2914265473
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42 |
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43 | 565 integrals
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44 | iter 1 energy = -74.6442059283 delta = 7.46913e-01
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45 | 565 integrals
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46 | iter 2 energy = -74.9411785471 delta = 2.32701e-01
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47 | 565 integrals
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48 | iter 3 energy = -74.9598835707 delta = 6.74768e-02
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49 | 565 integrals
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50 | iter 4 energy = -74.9608017389 delta = 1.82839e-02
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51 | 565 integrals
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52 | iter 5 energy = -74.9608457808 delta = 4.27179e-03
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53 | 565 integrals
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54 | iter 6 energy = -74.9608460189 delta = 2.87494e-04
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55 | 565 integrals
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56 | iter 7 energy = -74.9608460194 delta = 1.50392e-05
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57 |
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58 | HOMO is 1 B1 = -0.391179
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59 | LUMO is 4 A1 = 0.614055
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60 |
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61 | total scf energy = -74.9608460194
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62 |
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63 | Projecting the guess density.
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64 |
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65 | The number of electrons in the guess density = 10
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66 | Using symmetric orthogonalization.
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67 | n(basis): 11 2 4 7
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68 | Maximum orthogonalization residual = 3.72313
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69 | Minimum orthogonalization residual = 0.0336016
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70 | The number of electrons in the projected density = 9.96
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71 |
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72 | docc = [ 3 0 1 1 ]
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73 | nbasis = 24
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74 | MBPT2: auto-freezing 1 core orbitals
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75 |
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76 | Molecular formula H2O
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77 |
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78 | MPQC options:
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79 | matrixkit = <ReplSCMatrixKit>
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80 | filename = input_mp2h2o
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81 | restart_file = input_mp2h2o.ckpt
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82 | restart = no
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83 | checkpoint = no
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84 | savestate = no
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85 | do_energy = yes
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86 | do_gradient = no
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87 | optimize = no
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88 | write_pdb = no
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89 | print_mole = yes
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90 | print_timings = yes
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91 |
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92 | Entered memgrp based MP2 routine
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93 | nproc = 1
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94 | Memory available per node: 32000000 Bytes
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95 | Static memory used per node: 6528 Bytes
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96 | Total memory used per node: 187216 Bytes
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97 | Memory required for one pass: 187216 Bytes
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98 | Minimum memory required: 59920 Bytes
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99 | Batch size: 4
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100 | npass rest nbasis nshell nfuncmax
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101 | 1 0 24 11 5
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102 | nocc nvir nfzc nfzv
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103 | 5 19 1 0
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104 |
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105 | SCF::compute: energy accuracy = 1.0000000e-08
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106 |
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107 | integral intermediate storage = 533928 bytes
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108 | integral cache = 31461272 bytes
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109 | nuclear repulsion energy = 9.2914265473
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110 |
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111 | 31972 integrals
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112 | iter 1 energy = -75.8503496472 delta = 1.74984e-01
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113 | 31972 integrals
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114 | iter 2 energy = -76.0055105154 delta = 3.82513e-02
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115 | 31972 integrals
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116 | iter 3 energy = -76.0223842734 delta = 1.36626e-02
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117 | 31972 integrals
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118 | iter 4 energy = -76.0266339668 delta = 4.86921e-03
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119 | 31972 integrals
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120 | iter 5 energy = -76.0270157560 delta = 1.99984e-03
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121 | 31972 integrals
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122 | iter 6 energy = -76.0270275044 delta = 3.85947e-04
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123 | 31972 integrals
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124 | iter 7 energy = -76.0270276920 delta = 3.87047e-05
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125 | 31972 integrals
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126 | iter 8 energy = -76.0270277099 delta = 1.19426e-05
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127 | 31972 integrals
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128 | iter 9 energy = -76.0270277116 delta = 4.33708e-06
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129 | 31972 integrals
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130 | iter 10 energy = -76.0270277116 delta = 7.65241e-07
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131 | 31972 integrals
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132 | iter 11 energy = -76.0270277116 delta = 9.90937e-08
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133 | 31972 integrals
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134 | iter 12 energy = -76.0270277116 delta = 2.28152e-08
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135 |
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136 | HOMO is 1 B1 = -0.493537
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137 | LUMO is 4 A1 = 0.187487
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138 |
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139 | total scf energy = -76.0270277116
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140 |
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141 | Memory used for integral intermediates: 533928 Bytes
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142 | Memory used for integral storage: 7819714 Bytes
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143 | Size of global distributed array: 92160 Bytes
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144 | Beginning pass 1
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145 | Begin loop over shells (erep, 1.+2. q.t.)
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146 | working on shell pair ( 0 0), 6.2% complete
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147 | working on shell pair ( 2 1), 12.5% complete
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148 | working on shell pair ( 3 2), 18.8% complete
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149 | working on shell pair ( 4 2), 25.0% complete
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150 | working on shell pair ( 5 1), 31.2% complete
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151 | working on shell pair ( 5 5), 37.5% complete
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152 | working on shell pair ( 6 3), 43.8% complete
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153 | working on shell pair ( 7 0), 50.0% complete
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154 | working on shell pair ( 7 4), 56.2% complete
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155 | working on shell pair ( 8 0), 62.5% complete
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156 | working on shell pair ( 8 4), 68.8% complete
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157 | working on shell pair ( 8 8), 75.0% complete
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158 | working on shell pair ( 9 3), 81.2% complete
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159 | working on shell pair ( 9 7), 87.5% complete
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160 | working on shell pair ( 10 1), 93.8% complete
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161 | working on shell pair ( 10 5), 100.0% complete
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162 | working on shell pair ( 10 9), 106.2% complete
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163 | End of loop over shells
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164 | Begin third q.t.
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165 | End of third q.t.
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166 | Begin fourth q.t.
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167 | End of fourth q.t.
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168 |
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169 | Largest first order coefficients (unique):
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170 | 1 -0.04706000 1 B1 1 B1 -> 2 B1 2 B1 (+-+-)
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171 | 2 -0.03302648 3 A1 3 A1 -> 6 A1 6 A1 (+-+-)
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172 | 3 -0.02991689 1 B2 1 B2 -> 3 B2 3 B2 (+-+-)
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173 | 4 -0.02943706 1 B1 3 A1 -> 2 B1 6 A1 (+-+-)
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174 | 5 -0.02518844 1 B2 1 B2 -> 2 B2 2 B2 (+-+-)
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175 | 6 -0.02456297 1 B1 3 A1 -> 2 B1 6 A1 (++++)
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176 | 7 -0.02372933 1 B2 1 B2 -> 5 A1 5 A1 (+-+-)
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177 | 8 0.02319088 1 B1 1 B2 -> 2 B1 4 B2 (+-+-)
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178 | 9 -0.02254798 1 B1 1 B2 -> 2 B1 2 B2 (+-+-)
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179 | 10 -0.02168105 3 A1 3 A1 -> 3 B2 3 B2 (+-+-)
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180 |
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181 | RHF energy [au]: -76.027027711611
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182 | MP2 correlation energy [au]: -0.200804879172
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183 | MP2 energy [au]: -76.227832590783
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184 |
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185 | Value of the MolecularEnergy: -76.2278325908
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186 |
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187 | MBPT2:
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188 | Function Parameters:
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189 | value_accuracy = 9.249604e-07 (1.000000e-06) (computed)
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190 | gradient_accuracy = 0.000000e+00 (1.000000e-06)
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191 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
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192 |
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193 | Molecule:
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194 | Molecular formula: H2O
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195 | molecule<Molecule>: (
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196 | symmetry = c2v
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197 | symmetry_frame = [
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198 | [ -0.0000000000000000 0.0000000000000000 1.0000000000000000]
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199 | [ 1.0000000000000000 0.0000000000000000 -0.0000000000000000]
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200 | [ -0.0000000000000000 1.0000000000000000 -0.0000000000000000]]
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201 | unit = "angstrom"
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202 | { n atoms geometry }={
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203 | 1 O [ -0.0641272226 0.0000000000 0.0000000000]
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204 | 2 H [ 0.5088727774 -0.0000000000 0.7540000000]
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205 | 3 H [ 0.5088727774 -0.0000000000 -0.7540000000]
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206 | }
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207 | )
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208 | Atomic Masses:
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209 | 15.99491 1.00783 1.00783
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210 |
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211 | GaussianBasisSet:
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212 | nbasis = 24
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213 | nshell = 11
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214 | nprim = 24
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215 | name = "cc-pVDZ"
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216 | Reference Wavefunction:
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217 | Function Parameters:
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218 | value_accuracy = 9.249604e-09 (1.000000e-08) (computed)
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219 | gradient_accuracy = 0.000000e+00 (1.000000e-06)
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220 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
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221 |
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222 | Molecule:
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223 | Molecular formula: H2O
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224 | molecule<Molecule>: (
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225 | symmetry = c2v
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226 | symmetry_frame = [
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227 | [ -0.0000000000000000 0.0000000000000000 1.0000000000000000]
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228 | [ 1.0000000000000000 0.0000000000000000 -0.0000000000000000]
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229 | [ -0.0000000000000000 1.0000000000000000 -0.0000000000000000]]
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230 | unit = "angstrom"
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231 | { n atoms geometry }={
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232 | 1 O [ -0.0641272226 0.0000000000 0.0000000000]
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233 | 2 H [ 0.5088727774 -0.0000000000 0.7540000000]
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234 | 3 H [ 0.5088727774 -0.0000000000 -0.7540000000]
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235 | }
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236 | )
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237 | Atomic Masses:
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238 | 15.99491 1.00783 1.00783
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239 |
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240 | GaussianBasisSet:
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241 | nbasis = 24
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242 | nshell = 11
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243 | nprim = 24
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244 | name = "cc-pVDZ"
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245 | SCF Parameters:
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246 | maxiter = 40
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247 | density_reset_frequency = 10
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248 | level_shift = 0.000000
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249 |
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250 | CLSCF Parameters:
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251 | charge = 0
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252 | ndocc = 5
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253 | docc = [ 3 0 1 1 ]
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254 |
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255 |
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256 | The following keywords in "input_mp2h2o.in" were ignored:
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257 | mpqc:mole:total_charge
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258 |
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259 | CPU Wall
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260 | mpqc: 0.23 0.29
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261 | calc: 0.14 0.20
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262 | mp2-mem: 0.14 0.20
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263 | mp2 passes: 0.03 0.03
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264 | 3. q.t.: 0.00 0.00
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265 | 4. q.t.: 0.00 0.00
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266 | compute ecorr: 0.00 0.00
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267 | divide (ia|jb)'s: 0.00 0.00
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268 | erep+1.qt+2.qt: 0.02 0.03
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269 | vector: 0.08 0.13
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270 | density: 0.00 0.00
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271 | evals: 0.00 0.00
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272 | extrap: 0.01 0.01
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273 | fock: 0.04 0.09
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274 | accum: 0.00 0.00
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275 | ao_gmat: 0.01 0.06
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276 | start thread: 0.01 0.04
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277 | stop thread: 0.00 0.02
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278 | init pmax: 0.00 0.00
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279 | local data: 0.00 0.00
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280 | setup: 0.01 0.01
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281 | sum: 0.00 0.00
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282 | symm: 0.01 0.01
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283 | input: 0.08 0.09
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284 | vector: 0.02 0.02
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285 | density: 0.00 0.00
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286 | evals: 0.00 0.00
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287 | extrap: 0.00 0.00
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288 | fock: 0.01 0.01
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289 | accum: 0.00 0.00
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290 | ao_gmat: 0.00 0.00
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291 | start thread: 0.00 0.00
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292 | stop thread: 0.00 0.00
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293 | init pmax: 0.00 0.00
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294 | local data: 0.00 0.00
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295 | setup: 0.00 0.00
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296 | sum: 0.00 0.00
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297 | symm: 0.00 0.00
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298 |
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299 | End Time: Thu Dec 16 12:10:45 2004
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300 |
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