1 |
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2 | MPQC: Massively Parallel Quantum Chemistry
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3 | Version 2.1.0-alpha-gcc3
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4 |
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5 | Machine: i686-pc-linux-gnu
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6 | User: cljanss@aros.ca.sandia.gov
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7 | Start Time: Sat Apr 6 13:35:46 2002
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8 |
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9 | Using ProcMessageGrp for message passing (number of nodes = 1).
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10 | Using PthreadThreadGrp for threading (number of threads = 2).
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11 | Using ProcMemoryGrp for distributed shared memory.
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12 | Total number of processors = 2
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13 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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14 |
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15 | IntCoorGen: generated 3 coordinates.
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16 | Forming optimization coordinates:
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17 | SymmMolecularCoor::form_variable_coordinates()
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18 | expected 3 coordinates
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19 | found 2 variable coordinates
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20 | found 0 constant coordinates
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21 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
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22 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
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23 |
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24 | CLSCF::init: total charge = 0
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25 |
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26 | docc = [ 5 ]
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27 | nbasis = 7
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28 |
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29 | CLSCF::init: total charge = 0
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30 |
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31 | docc = [ 5 ]
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32 | nbasis = 7
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33 |
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34 | Molecular formula H2O
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35 |
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36 | MPQC options:
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37 | matrixkit = <ReplSCMatrixKit>
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38 | filename = h2ofrq_scfsto3gc2voptfrq
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39 | restart_file = h2ofrq_scfsto3gc2voptfrq.ckpt
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40 | restart = no
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41 | checkpoint = no
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42 | savestate = no
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43 | do_energy = yes
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44 | do_gradient = no
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45 | optimize = yes
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46 | write_pdb = no
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47 | print_mole = yes
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48 | print_timings = yes
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49 |
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50 | SCF::compute: energy accuracy = 1.0000000e-06
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51 |
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52 | integral intermediate storage = 31876 bytes
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53 | integral cache = 31967676 bytes
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54 | Using symmetric orthogonalization.
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55 | n(SO): 7
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56 | Maximum orthogonalization residual = 1.9104
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57 | Minimum orthogonalization residual = 0.344888
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58 | Using symmetric orthogonalization.
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59 | n(SO): 7
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60 | Maximum orthogonalization residual = 1.9104
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61 | Minimum orthogonalization residual = 0.344888
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62 | Using guess wavefunction as starting vector
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63 |
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64 | SCF::compute: energy accuracy = 1.0000000e-06
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65 |
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66 | integral intermediate storage = 31876 bytes
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67 | integral cache = 31967676 bytes
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68 | Starting from core Hamiltonian guess
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69 |
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70 | nuclear repulsion energy = 9.1571164588
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71 |
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72 | 733 integrals
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73 | iter 1 energy = -74.6468200575 delta = 7.47196e-01
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74 | 733 integrals
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75 | iter 2 energy = -74.9403205745 delta = 2.23216e-01
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76 | 733 integrals
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77 | iter 3 energy = -74.9595428818 delta = 6.69340e-02
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78 | 733 integrals
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79 | iter 4 energy = -74.9606520926 delta = 2.02576e-02
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80 | 733 integrals
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81 | iter 5 energy = -74.9607020706 delta = 4.09811e-03
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82 | 733 integrals
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83 | iter 6 energy = -74.9607024821 delta = 3.66040e-04
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84 | 733 integrals
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85 | iter 7 energy = -74.9607024827 delta = 1.47732e-05
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86 |
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87 | HOMO is 5 A = -0.386942
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88 | LUMO is 6 A = 0.592900
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89 |
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90 | total scf energy = -74.9607024827
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91 |
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92 | nuclear repulsion energy = 9.1571164588
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93 |
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94 | 733 integrals
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95 | iter 1 energy = -74.9607024827 delta = 7.72168e-01
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96 | 733 integrals
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97 | iter 2 energy = -74.9607024827 delta = 6.14966e-10
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98 |
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99 | HOMO is 5 A = -0.386942
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100 | LUMO is 6 A = 0.592900
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101 |
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102 | total scf energy = -74.9607024827
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103 |
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104 | SCF::compute: gradient accuracy = 1.0000000e-04
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105 |
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106 | Total Gradient:
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107 | 1 O -0.0000000000 0.0000000000 -0.0729842490
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108 | 2 H -0.0120904564 0.0000000000 0.0364921245
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109 | 3 H 0.0120904564 0.0000000000 0.0364921245
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110 |
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111 | Max Gradient : 0.0729842490 0.0001000000 no
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112 | Max Displacement : 0.1100275815 0.0001000000 no
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113 | Gradient*Displace: 0.0116038775 0.0001000000 no
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114 |
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115 | taking step of size 0.195457
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116 |
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117 | CLHF: changing atomic coordinates:
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118 | Molecular formula: H2O
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119 | molecule<Molecule>: (
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120 | symmetry = c1
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121 | unit = "angstrom"
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122 | { n atoms geometry }={
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123 | 1 O [ -0.0000000000 -0.0000000000 0.4275970369]
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124 | 2 H [ 0.7743131296 0.0000000000 -0.2137985184]
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125 | 3 H [ -0.7743131296 0.0000000000 -0.2137985184]
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126 | }
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127 | )
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128 | Atomic Masses:
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129 | 15.99491 1.00783 1.00783
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130 |
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131 | SCF::compute: energy accuracy = 6.0140210e-07
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132 |
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133 | integral intermediate storage = 31876 bytes
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134 | integral cache = 31967676 bytes
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135 | nuclear repulsion energy = 8.7625686681
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136 |
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137 | Using symmetric orthogonalization.
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138 | n(SO): 7
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139 | Maximum orthogonalization residual = 1.88345
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140 | Minimum orthogonalization residual = 0.373661
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141 | 733 integrals
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142 | iter 1 energy = -74.9600557457 delta = 7.66216e-01
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143 | 733 integrals
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144 | iter 2 energy = -74.9645681484 delta = 3.07904e-02
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145 | 733 integrals
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146 | iter 3 energy = -74.9652139114 delta = 1.22430e-02
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147 | 733 integrals
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148 | iter 4 energy = -74.9652936737 delta = 5.30781e-03
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149 | 733 integrals
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150 | iter 5 energy = -74.9652956044 delta = 6.65831e-04
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151 | 733 integrals
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152 | iter 6 energy = -74.9652956528 delta = 1.17553e-04
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153 | 733 integrals
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154 | iter 7 energy = -74.9652956528 delta = 5.13824e-07
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155 |
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156 | HOMO is 5 A = -0.391460
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157 | LUMO is 6 A = 0.565640
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158 |
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159 | total scf energy = -74.9652956528
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160 |
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161 | SCF::compute: gradient accuracy = 6.0140210e-05
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162 |
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163 | Total Gradient:
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164 | 1 O 0.0000000000 0.0000000000 0.0189281435
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165 | 2 H 0.0161925604 -0.0000000000 -0.0094640718
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166 | 3 H -0.0161925604 -0.0000000000 -0.0094640718
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167 |
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168 | Max Gradient : 0.0189281435 0.0001000000 no
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169 | Max Displacement : 0.0462248233 0.0001000000 no
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170 | Gradient*Displace: 0.0014817497 0.0001000000 no
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171 |
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172 | taking step of size 0.058908
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173 |
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174 | CLHF: changing atomic coordinates:
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175 | Molecular formula: H2O
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176 | molecule<Molecule>: (
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177 | symmetry = c1
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178 | unit = "angstrom"
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179 | { n atoms geometry }={
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180 | 1 O [ -0.0000000000 -0.0000000000 0.4278812074]
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181 | 2 H [ 0.7498520047 0.0000000000 -0.2139406037]
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182 | 3 H [ -0.7498520047 0.0000000000 -0.2139406037]
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183 | }
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184 | )
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185 | Atomic Masses:
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186 | 15.99491 1.00783 1.00783
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187 |
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188 | SCF::compute: energy accuracy = 2.1310519e-07
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189 |
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190 | integral intermediate storage = 31876 bytes
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191 | integral cache = 31967676 bytes
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192 | nuclear repulsion energy = 8.9310141606
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193 |
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194 | Using symmetric orthogonalization.
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195 | n(SO): 7
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196 | Maximum orthogonalization residual = 1.91335
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197 | Minimum orthogonalization residual = 0.361664
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198 | 733 integrals
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199 | iter 1 energy = -74.9655992543 delta = 7.79083e-01
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200 | 733 integrals
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201 | iter 2 energy = -74.9658114788 delta = 5.62911e-03
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202 | 733 integrals
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203 | iter 3 energy = -74.9658210078 delta = 1.05601e-03
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204 | 733 integrals
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205 | iter 4 energy = -74.9658214097 delta = 2.78062e-04
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206 | 733 integrals
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207 | iter 5 energy = -74.9658214119 delta = 1.59594e-05
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208 | 733 integrals
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209 | iter 6 energy = -74.9658214122 delta = 1.06676e-05
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210 |
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211 | HOMO is 5 A = -0.393473
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212 | LUMO is 6 A = 0.585729
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213 |
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214 | total scf energy = -74.9658214122
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215 |
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216 | SCF::compute: gradient accuracy = 2.1310519e-05
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217 |
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218 | Total Gradient:
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219 | 1 O 0.0000000000 -0.0000000000 0.0004917686
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220 | 2 H -0.0049560024 0.0000000000 -0.0002458843
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221 | 3 H 0.0049560024 -0.0000000000 -0.0002458843
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222 |
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223 | Max Gradient : 0.0049560024 0.0001000000 no
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224 | Max Displacement : 0.0166002180 0.0001000000 no
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225 | Gradient*Displace: 0.0001709563 0.0001000000 no
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226 |
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227 | taking step of size 0.022950
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228 |
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229 | CLHF: changing atomic coordinates:
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230 | Molecular formula: H2O
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231 | molecule<Molecule>: (
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232 | symmetry = c1
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233 | unit = "angstrom"
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234 | { n atoms geometry }={
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235 | 1 O [ -0.0000000000 -0.0000000000 0.4232792967]
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236 | 2 H [ 0.7586364624 -0.0000000000 -0.2116396483]
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237 | 3 H [ -0.7586364624 -0.0000000000 -0.2116396483]
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238 | }
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239 | )
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240 | Atomic Masses:
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241 | 15.99491 1.00783 1.00783
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242 |
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243 | SCF::compute: energy accuracy = 8.1481549e-08
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244 |
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245 | integral intermediate storage = 31876 bytes
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246 | integral cache = 31967676 bytes
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247 | nuclear repulsion energy = 8.9074557278
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248 |
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249 | Using symmetric orthogonalization.
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250 | n(SO): 7
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251 | Maximum orthogonalization residual = 1.9058
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252 | Minimum orthogonalization residual = 0.363085
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253 | 733 integrals
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254 | iter 1 energy = -74.9658760001 delta = 7.77075e-01
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255 | 733 integrals
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256 | iter 2 energy = -74.9658960905 delta = 1.56731e-03
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257 | 733 integrals
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258 | iter 3 energy = -74.9659002608 delta = 9.53666e-04
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259 | 733 integrals
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260 | iter 4 energy = -74.9659005409 delta = 3.41816e-04
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261 | 733 integrals
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262 | iter 5 energy = -74.9659005417 delta = 1.22645e-05
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263 | 733 integrals
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264 | iter 6 energy = -74.9659005417 delta = 5.60889e-07
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265 |
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266 | HOMO is 5 A = -0.392545
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267 | LUMO is 6 A = 0.581747
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268 |
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269 | total scf energy = -74.9659005417
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270 |
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271 | SCF::compute: gradient accuracy = 8.1481549e-06
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272 |
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273 | Total Gradient:
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274 | 1 O -0.0000000000 -0.0000000000 -0.0006048632
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275 | 2 H 0.0001386420 0.0000000000 0.0003024316
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276 | 3 H -0.0001386420 -0.0000000000 0.0003024316
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277 |
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278 | Max Gradient : 0.0006048632 0.0001000000 no
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279 | Max Displacement : 0.0011699905 0.0001000000 no
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280 | Gradient*Displace: 0.0000013466 0.0001000000 yes
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281 |
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282 | taking step of size 0.002198
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283 |
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284 | CLHF: changing atomic coordinates:
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285 | Molecular formula: H2O
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286 | molecule<Molecule>: (
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287 | symmetry = c1
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288 | unit = "angstrom"
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289 | { n atoms geometry }={
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290 | 1 O [ -0.0000000000 -0.0000000000 0.4238984290]
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291 | 2 H [ 0.7580924982 -0.0000000000 -0.2119492145]
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292 | 3 H [ -0.7580924982 -0.0000000000 -0.2119492145]
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293 | }
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294 | )
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295 | Atomic Masses:
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296 | 15.99491 1.00783 1.00783
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297 |
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298 | SCF::compute: energy accuracy = 4.8212102e-09
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299 |
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300 | integral intermediate storage = 31876 bytes
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301 | integral cache = 31967676 bytes
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302 | nuclear repulsion energy = 8.9061536070
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303 |
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304 | Using symmetric orthogonalization.
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305 | n(SO): 7
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306 | Maximum orthogonalization residual = 1.90602
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307 | Minimum orthogonalization residual = 0.363205
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308 | 733 integrals
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309 | iter 1 energy = -74.9659007700 delta = 7.76697e-01
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310 | 733 integrals
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311 | iter 2 energy = -74.9659011131 delta = 2.61340e-04
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312 | 733 integrals
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313 | iter 3 energy = -74.9659011859 delta = 1.48080e-04
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314 | 733 integrals
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315 | iter 4 energy = -74.9659011889 delta = 3.21369e-05
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316 | 733 integrals
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317 | iter 5 energy = -74.9659011889 delta = 2.79415e-06
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318 | 731 integrals
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319 | iter 6 energy = -74.9659011888 delta = 3.45305e-07
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320 |
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321 | HOMO is 5 A = -0.392617
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322 | LUMO is 6 A = 0.581763
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323 |
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324 | total scf energy = -74.9659011888
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325 |
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326 | SCF::compute: gradient accuracy = 4.8212102e-07
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327 |
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328 | Total Gradient:
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329 | 1 O -0.0000000000 -0.0000000000 0.0000640341
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330 | 2 H 0.0000291212 0.0000000000 -0.0000320170
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331 | 3 H -0.0000291212 -0.0000000000 -0.0000320170
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332 |
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333 | Max Gradient : 0.0000640341 0.0001000000 yes
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334 | Max Displacement : 0.0000580782 0.0001000000 yes
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335 | Gradient*Displace: 0.0000000071 0.0001000000 yes
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336 |
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337 | All convergence criteria have been met.
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338 | The optimization has converged.
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339 |
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340 | Value of the MolecularEnergy: -74.9659011888
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341 |
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342 | The external rank is 6
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343 | Computing molecular hessian from 6 displacements:
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344 | Starting at displacement: 0
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345 | Hessian options:
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346 | displacement: 0.01 bohr
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347 | gradient_accuracy: 1e-05 au
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348 | eliminate_cubic_terms: yes
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349 | only_totally_symmetric: no
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350 |
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351 | Beginning displacement 0:
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352 | Molecule: setting point group to c1
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353 | Displacement is A1 in c2v. Using point group c1 for displaced molecule.
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354 |
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355 | SCF::compute: energy accuracy = 1.0000000e-07
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356 |
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357 | integral intermediate storage = 31876 bytes
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358 | integral cache = 31967676 bytes
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359 | nuclear repulsion energy = 8.9061536070
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360 |
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361 | Using symmetric orthogonalization.
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362 | n(SO): 7
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363 | Maximum orthogonalization residual = 1.90602
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364 | Minimum orthogonalization residual = 0.363205
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365 | 733 integrals
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366 | iter 1 energy = -74.9659011889 delta = 7.76791e-01
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367 | 733 integrals
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368 | iter 2 energy = -74.9659011889 delta = 4.78834e-11
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369 |
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370 | HOMO is 5 A = -0.392617
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371 | LUMO is 6 A = 0.581763
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372 |
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373 | total scf energy = -74.9659011889
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374 |
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375 | SCF::compute: gradient accuracy = 1.0000000e-05
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376 |
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377 | Total Gradient:
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378 | 1 O -0.0000000000 -0.0000000000 0.0000640341
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379 | 2 H 0.0000291212 0.0000000000 -0.0000320171
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380 | 3 H -0.0000291212 -0.0000000000 -0.0000320171
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381 |
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382 | Beginning displacement 1:
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383 | Molecule: setting point group to c1
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384 | Displacement is A1 in c2v. Using point group c1 for displaced molecule.
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385 |
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386 | SCF::compute: energy accuracy = 1.0000000e-07
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387 |
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388 | integral intermediate storage = 31876 bytes
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389 | integral cache = 31967676 bytes
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390 | nuclear repulsion energy = 8.9017652169
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391 |
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392 | Using symmetric orthogonalization.
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393 | n(SO): 7
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394 | Maximum orthogonalization residual = 1.90738
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395 | Minimum orthogonalization residual = 0.363655
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396 | 733 integrals
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397 | iter 1 energy = -74.9658762357 delta = 7.76615e-01
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398 | 733 integrals
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399 | iter 2 energy = -74.9658835013 delta = 1.18413e-03
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400 | 733 integrals
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401 | iter 3 energy = -74.9658851062 delta = 7.15106e-04
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402 | 733 integrals
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403 | iter 4 energy = -74.9658851505 delta = 1.22961e-04
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404 | 733 integrals
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405 | iter 5 energy = -74.9658851510 delta = 1.04249e-05
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406 | 731 integrals
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407 | iter 6 energy = -74.9658851506 delta = 1.26702e-06
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408 |
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409 | HOMO is 5 A = -0.392971
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410 | LUMO is 6 A = 0.582017
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411 |
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412 | total scf energy = -74.9658851506
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413 |
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414 | SCF::compute: gradient accuracy = 1.0000000e-05
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415 |
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416 | Total Gradient:
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417 | 1 O -0.0000000000 -0.0000000000 0.0029890656
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418 | 2 H -0.0007094581 0.0000000000 -0.0014945328
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419 | 3 H 0.0007094581 -0.0000000000 -0.0014945328
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420 |
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421 | Beginning displacement 2:
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422 | Molecule: setting point group to c1
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423 | Displacement is A1 in c2v. Using point group c1 for displaced molecule.
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424 |
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425 | SCF::compute: energy accuracy = 1.0000000e-07
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426 |
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427 | integral intermediate storage = 31876 bytes
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428 | integral cache = 31967676 bytes
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429 | nuclear repulsion energy = 8.9508812501
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430 |
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431 | Using symmetric orthogonalization.
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432 | n(SO): 7
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433 | Maximum orthogonalization residual = 1.91146
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434 | Minimum orthogonalization residual = 0.359915
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435 | 733 integrals
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436 | iter 1 energy = -74.9657834852 delta = 7.77902e-01
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437 | 733 integrals
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---|
438 | iter 2 energy = -74.9658377567 delta = 3.47008e-03
|
---|
439 | 733 integrals
|
---|
440 | iter 3 energy = -74.9658450691 delta = 1.31938e-03
|
---|
441 | 733 integrals
|
---|
442 | iter 4 energy = -74.9658459457 delta = 5.58077e-04
|
---|
443 | 733 integrals
|
---|
444 | iter 5 energy = -74.9658459678 delta = 7.35883e-05
|
---|
445 | 733 integrals
|
---|
446 | iter 6 energy = -74.9658459683 delta = 1.18429e-05
|
---|
447 |
|
---|
448 | HOMO is 5 A = -0.392701
|
---|
449 | LUMO is 6 A = 0.586163
|
---|
450 |
|
---|
451 | total scf energy = -74.9658459683
|
---|
452 |
|
---|
453 | SCF::compute: gradient accuracy = 1.0000000e-05
|
---|
454 |
|
---|
455 | Total Gradient:
|
---|
456 | 1 O -0.0000000000 -0.0000000000 -0.0078502085
|
---|
457 | 2 H -0.0042547284 0.0000000000 0.0039251043
|
---|
458 | 3 H 0.0042547284 -0.0000000000 0.0039251043
|
---|
459 |
|
---|
460 | Beginning displacement 3:
|
---|
461 | Molecule: setting point group to c1
|
---|
462 | Displacement is A1 in c2v. Using point group c1 for displaced molecule.
|
---|
463 |
|
---|
464 | SCF::compute: energy accuracy = 1.0000000e-07
|
---|
465 |
|
---|
466 | integral intermediate storage = 31876 bytes
|
---|
467 | integral cache = 31967676 bytes
|
---|
468 | nuclear repulsion energy = 8.9103309454
|
---|
469 |
|
---|
470 | Using symmetric orthogonalization.
|
---|
471 | n(SO): 7
|
---|
472 | Maximum orthogonalization residual = 1.90465
|
---|
473 | Minimum orthogonalization residual = 0.362783
|
---|
474 | 733 integrals
|
---|
475 | iter 1 energy = -74.9658726258 delta = 7.76047e-01
|
---|
476 | 733 integrals
|
---|
477 | iter 2 energy = -74.9658850747 delta = 1.41184e-03
|
---|
478 | 733 integrals
|
---|
479 | iter 3 energy = -74.9658856405 delta = 2.86074e-04
|
---|
480 | 733 integrals
|
---|
481 | iter 4 energy = -74.9658856659 delta = 8.51254e-05
|
---|
482 | 733 integrals
|
---|
483 | iter 5 energy = -74.9658856661 delta = 6.25004e-06
|
---|
484 | 733 integrals
|
---|
485 | iter 6 energy = -74.9658856661 delta = 4.11396e-06
|
---|
486 |
|
---|
487 | HOMO is 5 A = -0.392253
|
---|
488 | LUMO is 6 A = 0.581454
|
---|
489 |
|
---|
490 | total scf energy = -74.9658856661
|
---|
491 |
|
---|
492 | SCF::compute: gradient accuracy = 1.0000000e-05
|
---|
493 |
|
---|
494 | Total Gradient:
|
---|
495 | 1 O -0.0000000000 -0.0000000000 -0.0028306959
|
---|
496 | 2 H 0.0007678399 0.0000000000 0.0014153479
|
---|
497 | 3 H -0.0007678399 -0.0000000000 0.0014153479
|
---|
498 |
|
---|
499 | Beginning displacement 4:
|
---|
500 | Molecule: setting point group to c1
|
---|
501 | Displacement is A1 in c2v. Using point group c1 for displaced molecule.
|
---|
502 |
|
---|
503 | SCF::compute: energy accuracy = 1.0000000e-07
|
---|
504 |
|
---|
505 | integral intermediate storage = 31876 bytes
|
---|
506 | integral cache = 31967676 bytes
|
---|
507 | nuclear repulsion energy = 8.8618348904
|
---|
508 |
|
---|
509 | Using symmetric orthogonalization.
|
---|
510 | n(SO): 7
|
---|
511 | Maximum orthogonalization residual = 1.9006
|
---|
512 | Minimum orthogonalization residual = 0.366497
|
---|
513 | 733 integrals
|
---|
514 | iter 1 energy = -74.9657839616 delta = 7.75732e-01
|
---|
515 | 733 integrals
|
---|
516 | iter 2 energy = -74.9658370780 delta = 3.40098e-03
|
---|
517 | 733 integrals
|
---|
518 | iter 3 energy = -74.9658442546 delta = 1.29084e-03
|
---|
519 | 733 integrals
|
---|
520 | iter 4 energy = -74.9658451392 delta = 5.55750e-04
|
---|
521 | 733 integrals
|
---|
522 | iter 5 energy = -74.9658451628 delta = 7.50195e-05
|
---|
523 | 733 integrals
|
---|
524 | iter 6 energy = -74.9658451634 delta = 1.30350e-05
|
---|
525 |
|
---|
526 | HOMO is 5 A = -0.392544
|
---|
527 | LUMO is 6 A = 0.577386
|
---|
528 |
|
---|
529 | total scf energy = -74.9658451634
|
---|
530 |
|
---|
531 | SCF::compute: gradient accuracy = 1.0000000e-05
|
---|
532 |
|
---|
533 | Total Gradient:
|
---|
534 | 1 O 0.0000000000 -0.0000000000 0.0078142156
|
---|
535 | 2 H 0.0041813176 0.0000000000 -0.0039071078
|
---|
536 | 3 H -0.0041813176 -0.0000000000 -0.0039071078
|
---|
537 |
|
---|
538 | Beginning displacement 5:
|
---|
539 | Displacement is B1 in c2v. Using point group c1 for displaced molecule.
|
---|
540 |
|
---|
541 | SCF::compute: energy accuracy = 1.0000000e-07
|
---|
542 |
|
---|
543 | integral intermediate storage = 31876 bytes
|
---|
544 | integral cache = 31967676 bytes
|
---|
545 | nuclear repulsion energy = 8.9063915734
|
---|
546 |
|
---|
547 | Using symmetric orthogonalization.
|
---|
548 | n(SO): 7
|
---|
549 | Maximum orthogonalization residual = 1.90605
|
---|
550 | Minimum orthogonalization residual = 0.363005
|
---|
551 | 733 integrals
|
---|
552 | iter 1 energy = -74.9657678554 delta = 7.77729e-01
|
---|
553 | 733 integrals
|
---|
554 | iter 2 energy = -74.9658225593 delta = 2.80290e-03
|
---|
555 | 733 integrals
|
---|
556 | iter 3 energy = -74.9658263905 delta = 8.21381e-04
|
---|
557 | 733 integrals
|
---|
558 | iter 4 energy = -74.9658267503 delta = 3.27011e-04
|
---|
559 | 733 integrals
|
---|
560 | iter 5 energy = -74.9658267669 delta = 6.55565e-05
|
---|
561 | 733 integrals
|
---|
562 | iter 6 energy = -74.9658267676 delta = 1.38789e-05
|
---|
563 | 733 integrals
|
---|
564 | iter 7 energy = -74.9658267676 delta = 8.86547e-07
|
---|
565 | 733 integrals
|
---|
566 | iter 8 energy = -74.9658267676 delta = 2.78572e-07
|
---|
567 |
|
---|
568 | HOMO is 5 A = -0.392624
|
---|
569 | LUMO is 6 A = 0.581491
|
---|
570 |
|
---|
571 | total scf energy = -74.9658267676
|
---|
572 |
|
---|
573 | SCF::compute: gradient accuracy = 1.0000000e-05
|
---|
574 |
|
---|
575 | Total Gradient:
|
---|
576 | 1 O 0.0109383730 -0.0000000000 -0.0000910837
|
---|
577 | 2 H -0.0055098015 0.0000000000 0.0046330688
|
---|
578 | 3 H -0.0054285715 -0.0000000000 -0.0045419850
|
---|
579 | The external rank is 6
|
---|
580 |
|
---|
581 | Frequencies (cm-1; negative is imaginary):
|
---|
582 | A1
|
---|
583 | 1 4139.82
|
---|
584 | 2 2170.12
|
---|
585 |
|
---|
586 | B1
|
---|
587 | 3 4390.84
|
---|
588 |
|
---|
589 | THERMODYNAMIC ANALYSIS:
|
---|
590 |
|
---|
591 | Contributions to the nonelectronic enthalpy at 298.15 K:
|
---|
592 | kJ/mol kcal/mol
|
---|
593 | E0vib = 64.0049 15.2975
|
---|
594 | Evib(T) = 0.0007 0.0002
|
---|
595 | Erot(T) = 3.7185 0.8887
|
---|
596 | Etrans(T) = 3.7185 0.8887
|
---|
597 | PV(T) = 2.4790 0.5925
|
---|
598 | Total nonelectronic enthalpy:
|
---|
599 | H_nonel(T) = 73.9215 17.6677
|
---|
600 |
|
---|
601 | Contributions to the entropy at 298.15 K and 1.0 atm:
|
---|
602 | J/(mol*K) cal/(mol*K)
|
---|
603 | S_trans(T,P) = 144.8020 34.6085
|
---|
604 | S_rot(T) = 44.6554 10.6729
|
---|
605 | S_vib(T) = 0.0027 0.0006
|
---|
606 | S_el = 0.0000 0.0000
|
---|
607 | Total entropy:
|
---|
608 | S_total(T,P) = 189.4601 45.2820
|
---|
609 |
|
---|
610 | Various data used for thermodynamic analysis:
|
---|
611 |
|
---|
612 | Nonlinear molecule
|
---|
613 | Principal moments of inertia (amu*angstrom^2): 0.72373, 1.15840, 1.88213
|
---|
614 | Point group: c2v
|
---|
615 | Order of point group: 4
|
---|
616 | Rotational symmetry number: 2
|
---|
617 | Rotational temperatures (K): 33.5129, 20.9377, 12.8866
|
---|
618 | Electronic degeneracy: 1
|
---|
619 |
|
---|
620 | Function Parameters:
|
---|
621 | value_accuracy = 2.075779e-08 (1.000000e-07)
|
---|
622 | gradient_accuracy = 2.075779e-06 (4.821210e-07)
|
---|
623 | hessian_accuracy = 0.000000e+00 (1.000000e-04) (computed)
|
---|
624 |
|
---|
625 | Molecular Coordinates:
|
---|
626 | IntMolecularCoor Parameters:
|
---|
627 | update_bmat = no
|
---|
628 | scale_bonds = 1
|
---|
629 | scale_bends = 1
|
---|
630 | scale_tors = 1
|
---|
631 | scale_outs = 1
|
---|
632 | symmetry_tolerance = 1.000000e-05
|
---|
633 | simple_tolerance = 1.000000e-03
|
---|
634 | coordinate_tolerance = 1.000000e-07
|
---|
635 | have_fixed_values = 0
|
---|
636 | max_update_steps = 100
|
---|
637 | max_update_disp = 0.500000
|
---|
638 | have_fixed_values = 0
|
---|
639 |
|
---|
640 | Molecular formula: H2O
|
---|
641 | molecule<Molecule>: (
|
---|
642 | symmetry = c1
|
---|
643 | unit = "angstrom"
|
---|
644 | { n atoms geometry }={
|
---|
645 | 1 O [ -0.0000000000 -0.0000000000 0.4238984290]
|
---|
646 | 2 H [ 0.7580924982 -0.0000000000 -0.2119492145]
|
---|
647 | 3 H [ -0.7580924982 -0.0000000000 -0.2119492145]
|
---|
648 | }
|
---|
649 | )
|
---|
650 | Atomic Masses:
|
---|
651 | 15.99491 1.00783 1.00783
|
---|
652 |
|
---|
653 | Bonds:
|
---|
654 | STRE s1 0.98945 1 2 O-H
|
---|
655 | STRE s2 0.98945 1 3 O-H
|
---|
656 | Bends:
|
---|
657 | BEND b1 100.02373 2 1 3 H-O-H
|
---|
658 |
|
---|
659 | SymmMolecularCoor Parameters:
|
---|
660 | change_coordinates = no
|
---|
661 | transform_hessian = yes
|
---|
662 | max_kappa2 = 10.000000
|
---|
663 |
|
---|
664 | GaussianBasisSet:
|
---|
665 | nbasis = 7
|
---|
666 | nshell = 4
|
---|
667 | nprim = 12
|
---|
668 | name = "STO-3G"
|
---|
669 |
|
---|
670 | SCF::compute: energy accuracy = 1.0000000e-07
|
---|
671 |
|
---|
672 | integral intermediate storage = 31876 bytes
|
---|
673 | integral cache = 31967676 bytes
|
---|
674 | nuclear repulsion energy = 8.9061536070
|
---|
675 |
|
---|
676 | Using symmetric orthogonalization.
|
---|
677 | n(SO): 7
|
---|
678 | Maximum orthogonalization residual = 1.90602
|
---|
679 | Minimum orthogonalization residual = 0.363205
|
---|
680 | 733 integrals
|
---|
681 | iter 1 energy = -74.9658709402 delta = 7.76790e-01
|
---|
682 | 733 integrals
|
---|
683 | iter 2 energy = -74.9658997032 delta = 1.50404e-03
|
---|
684 | 733 integrals
|
---|
685 | iter 3 energy = -74.9659011256 delta = 3.76760e-04
|
---|
686 | 733 integrals
|
---|
687 | iter 4 energy = -74.9659011875 delta = 9.05876e-05
|
---|
688 | 733 integrals
|
---|
689 | iter 5 energy = -74.9659011889 delta = 1.70143e-05
|
---|
690 | 733 integrals
|
---|
691 | iter 6 energy = -74.9659011889 delta = 5.76397e-07
|
---|
692 |
|
---|
693 | HOMO is 5 A = -0.392617
|
---|
694 | LUMO is 6 A = 0.581763
|
---|
695 |
|
---|
696 | total scf energy = -74.9659011889
|
---|
697 | Natural Population Analysis:
|
---|
698 | n atom charge ne(S) ne(P)
|
---|
699 | 1 O -0.365860 3.772732 4.593129
|
---|
700 | 2 H 0.182930 0.817070
|
---|
701 | 3 H 0.182930 0.817070
|
---|
702 |
|
---|
703 | SCF Parameters:
|
---|
704 | maxiter = 40
|
---|
705 | density_reset_frequency = 10
|
---|
706 | level_shift = 0.000000
|
---|
707 |
|
---|
708 | CLSCF Parameters:
|
---|
709 | charge = 0
|
---|
710 | ndocc = 5
|
---|
711 | docc = [ 5 ]
|
---|
712 |
|
---|
713 | The following keywords in "h2ofrq_scfsto3gc2voptfrq.in" were ignored:
|
---|
714 | mpqc:mole:guess_wavefunction:multiplicity
|
---|
715 | mpqc:mole:multiplicity
|
---|
716 |
|
---|
717 | CPU Wall
|
---|
718 | mpqc: 0.78 0.81
|
---|
719 | NAO: 0.03 0.03
|
---|
720 | vector: 0.02 0.02
|
---|
721 | density: 0.00 0.00
|
---|
722 | evals: 0.00 0.00
|
---|
723 | extrap: 0.00 0.00
|
---|
724 | fock: 0.00 0.01
|
---|
725 | accum: 0.00 0.00
|
---|
726 | ao_gmat: 0.00 0.01
|
---|
727 | start thread: 0.00 0.00
|
---|
728 | stop thread: 0.00 0.00
|
---|
729 | init pmax: 0.00 0.00
|
---|
730 | local data: 0.00 0.00
|
---|
731 | setup: 0.00 0.00
|
---|
732 | sum: 0.00 0.00
|
---|
733 | symm: 0.00 0.00
|
---|
734 | calc: 0.29 0.31
|
---|
735 | compute gradient: 0.15 0.16
|
---|
736 | nuc rep: 0.00 0.00
|
---|
737 | one electron gradient: 0.03 0.02
|
---|
738 | overlap gradient: 0.00 0.01
|
---|
739 | two electron gradient: 0.12 0.14
|
---|
740 | contribution: 0.01 0.03
|
---|
741 | start thread: 0.01 0.03
|
---|
742 | stop thread: 0.00 0.00
|
---|
743 | setup: 0.11 0.11
|
---|
744 | vector: 0.12 0.13
|
---|
745 | density: 0.00 0.00
|
---|
746 | evals: 0.01 0.01
|
---|
747 | extrap: 0.01 0.01
|
---|
748 | fock: 0.03 0.03
|
---|
749 | accum: 0.00 0.00
|
---|
750 | ao_gmat: 0.02 0.03
|
---|
751 | start thread: 0.02 0.02
|
---|
752 | stop thread: 0.00 0.00
|
---|
753 | init pmax: 0.00 0.00
|
---|
754 | local data: 0.00 0.00
|
---|
755 | setup: 0.00 0.00
|
---|
756 | sum: 0.00 0.00
|
---|
757 | symm: 0.00 0.00
|
---|
758 | vector: 0.02 0.02
|
---|
759 | density: 0.00 0.00
|
---|
760 | evals: 0.00 0.00
|
---|
761 | extrap: 0.01 0.00
|
---|
762 | fock: 0.00 0.01
|
---|
763 | accum: 0.00 0.00
|
---|
764 | ao_gmat: 0.00 0.01
|
---|
765 | start thread: 0.00 0.00
|
---|
766 | stop thread: 0.00 0.00
|
---|
767 | init pmax: 0.00 0.00
|
---|
768 | local data: 0.00 0.00
|
---|
769 | setup: 0.00 0.00
|
---|
770 | sum: 0.00 0.00
|
---|
771 | symm: 0.00 0.00
|
---|
772 | hessian: 0.32 0.34
|
---|
773 | compute gradient: 0.20 0.20
|
---|
774 | nuc rep: 0.00 0.00
|
---|
775 | one electron gradient: 0.02 0.02
|
---|
776 | overlap gradient: 0.02 0.01
|
---|
777 | two electron gradient: 0.16 0.17
|
---|
778 | contribution: 0.03 0.04
|
---|
779 | start thread: 0.03 0.03
|
---|
780 | stop thread: 0.00 0.00
|
---|
781 | setup: 0.13 0.13
|
---|
782 | vector: 0.12 0.13
|
---|
783 | density: 0.01 0.00
|
---|
784 | evals: 0.00 0.01
|
---|
785 | extrap: 0.03 0.02
|
---|
786 | fock: 0.03 0.04
|
---|
787 | accum: 0.00 0.00
|
---|
788 | ao_gmat: 0.02 0.03
|
---|
789 | start thread: 0.02 0.02
|
---|
790 | stop thread: 0.00 0.00
|
---|
791 | init pmax: 0.00 0.00
|
---|
792 | local data: 0.00 0.00
|
---|
793 | setup: 0.00 0.00
|
---|
794 | sum: 0.01 0.00
|
---|
795 | symm: 0.00 0.00
|
---|
796 | input: 0.13 0.13
|
---|
797 |
|
---|
798 | End Time: Sat Apr 6 13:35:47 2002
|
---|
799 |
|
---|