1 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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2 |
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3 | MPQC: Massively Parallel Quantum Chemistry
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4 | Version 2.1.0-alpha-gcc3
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5 |
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6 | Machine: i686-pc-linux-gnu
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7 | User: cljanss@aros.ca.sandia.gov
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8 | Start Time: Sat Apr 6 14:01:04 2002
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9 |
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10 | Using ProcMessageGrp for message passing (number of nodes = 1).
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11 | Using PthreadThreadGrp for threading (number of threads = 2).
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12 | Using ProcMemoryGrp for distributed shared memory.
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13 | Total number of processors = 2
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14 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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15 | Molecule: setting point group to c2v
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16 |
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17 | IntCoorGen: generated 3 coordinates.
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18 | Forming optimization coordinates:
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19 | SymmMolecularCoor::form_variable_coordinates()
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20 | expected 3 coordinates
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21 | found 2 variable coordinates
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22 | found 0 constant coordinates
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23 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/6-31gS.kv.
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24 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
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25 |
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26 | HSOSSCF::init: total charge = 0
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27 |
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28 | Starting from core Hamiltonian guess
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29 |
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30 | Using symmetric orthogonalization.
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31 | n(SO): 4 0 1 2
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32 | Maximum orthogonalization residual = 1.94235
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33 | Minimum orthogonalization residual = 0.275215
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34 | docc = [ 2 0 0 1 ]
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35 | socc = [ 1 0 1 0 ]
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36 |
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37 | HSOSSCF::init: total charge = 0
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38 |
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39 | Projecting guess wavefunction into the present basis set
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40 |
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41 | SCF::compute: energy accuracy = 1.0000000e-06
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42 |
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43 | nuclear repulsion energy = 6.0605491858
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44 |
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45 | iter 1 energy = -38.1820699187 delta = 5.64824e-01
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46 | iter 2 energy = -38.4083575544 delta = 1.45984e-01
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47 | iter 3 energy = -38.4168336215 delta = 3.56591e-02
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48 | iter 4 energy = -38.4175716540 delta = 1.01929e-02
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49 | iter 5 energy = -38.4176486511 delta = 4.37691e-03
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50 | iter 6 energy = -38.4176552372 delta = 6.66000e-04
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51 | iter 7 energy = -38.4176560606 delta = 2.30956e-04
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52 | iter 8 energy = -38.4176560751 delta = 4.38489e-05
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53 | iter 9 energy = -38.4176560764 delta = 1.13693e-05
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54 | iter 10 energy = -38.4176560765 delta = 3.21030e-06
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55 |
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56 | HOMO is 1 B1 = 0.003112
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57 | LUMO is 2 B2 = 0.704260
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58 |
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59 | total scf energy = -38.4176560765
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60 |
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61 | Projecting the guess density.
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62 |
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63 | The number of electrons in the guess density = 8
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64 | Using symmetric orthogonalization.
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65 | n(SO): 10 1 3 5
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66 | Maximum orthogonalization residual = 4.63968
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67 | Minimum orthogonalization residual = 0.0296946
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68 | The number of electrons in the projected density = 7.9909
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69 |
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70 | docc = [ 2 0 0 1 ]
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71 | socc = [ 1 0 1 0 ]
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72 |
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73 | Molecular formula CH2
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74 |
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75 | MPQC options:
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76 | matrixkit = <ReplSCMatrixKit>
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77 | filename = input_rksch2
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78 | restart_file = input_rksch2.ckpt
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79 | restart = no
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80 | checkpoint = no
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81 | savestate = no
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82 | do_energy = yes
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83 | do_gradient = no
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84 | optimize = yes
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85 | write_pdb = no
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86 | print_mole = yes
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87 | print_timings = yes
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88 |
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89 | SCF::compute: energy accuracy = 1.0000000e-06
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90 |
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91 | Initializing ShellExtent
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92 | nshell = 8
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93 | ncell = 30690
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94 | ave nsh/cell = 1.81848
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95 | max nsh/cell = 8
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96 | nuclear repulsion energy = 6.0605491858
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97 |
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98 | Total integration points = 4049
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99 | Integrated electron density error = -0.000044724621
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100 | iter 1 energy = -38.4525062305 delta = 1.79777e-01
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101 | Total integration points = 11317
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102 | Integrated electron density error = -0.000000985533
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103 | iter 2 energy = -38.5170918956 delta = 3.50152e-02
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104 | Total integration points = 11317
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105 | Integrated electron density error = -0.000000741841
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106 | iter 3 energy = -38.5205187054 delta = 8.97975e-03
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107 | Total integration points = 24639
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108 | Integrated electron density error = -0.000001535453
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109 | iter 4 energy = -38.5212195276 delta = 2.93539e-03
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110 | Total integration points = 24639
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111 | Integrated electron density error = -0.000001551850
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112 | iter 5 energy = -38.5212320152 delta = 5.25152e-04
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113 | Total integration points = 46071
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114 | Integrated electron density error = -0.000000047648
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115 | iter 6 energy = -38.5212337022 delta = 1.34258e-04
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116 | Total integration points = 46071
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117 | Integrated electron density error = -0.000000047666
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118 | iter 7 energy = -38.5212337540 delta = 3.11841e-05
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119 | Total integration points = 46071
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120 | Integrated electron density error = -0.000000047675
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121 | iter 8 energy = -38.5212337677 delta = 1.29812e-05
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122 | Total integration points = 46071
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123 | Integrated electron density error = -0.000000047677
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124 | iter 9 energy = -38.5212337686 delta = 3.61784e-06
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125 |
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126 | HOMO is 1 B1 = -0.098757
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127 | LUMO is 4 A1 = 0.136937
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128 |
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129 | total scf energy = -38.5212337686
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130 |
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131 | SCF::compute: gradient accuracy = 1.0000000e-04
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132 |
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133 | Initializing ShellExtent
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134 | nshell = 8
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135 | ncell = 30690
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136 | ave nsh/cell = 1.81848
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137 | max nsh/cell = 8
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138 | Total integration points = 46071
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139 | Integrated electron density error = -0.000000087909
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140 | Total Gradient:
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141 | 1 C 0.0000000000 0.0000000002 -0.0436823762
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142 | 2 H 0.0000000001 -0.0213229360 0.0218411880
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143 | 3 H -0.0000000001 0.0213229358 0.0218411882
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144 |
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145 | Max Gradient : 0.0436823762 0.0001000000 no
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146 | Max Displacement : 0.1471097774 0.0001000000 no
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147 | Gradient*Displace: 0.0145309562 0.0001000000 no
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148 |
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149 | taking step of size 0.229447
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150 |
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151 | HSOSKS: changing atomic coordinates:
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152 | Molecular formula: CH2
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153 | molecule<Molecule>: (
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154 | symmetry = c2v
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155 | unit = "angstrom"
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156 | { n atoms geometry }={
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157 | 1 C [ 0.0000000000 0.0000000000 -0.0334073756]
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158 | 2 H [ -0.0000000000 0.9348471473 0.5625616205]
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159 | 3 H [ -0.0000000000 -0.9348471473 0.5625616205]
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160 | }
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161 | )
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162 | Atomic Masses:
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163 | 12.00000 1.00783 1.00783
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164 |
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165 | SCF::compute: energy accuracy = 5.7011379e-07
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166 |
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167 | Initializing ShellExtent
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168 | nshell = 8
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169 | ncell = 30690
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170 | ave nsh/cell = 1.82007
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171 | max nsh/cell = 8
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172 | nuclear repulsion energy = 6.0107988773
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173 |
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174 | Using symmetric orthogonalization.
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175 | n(SO): 10 1 3 5
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176 | Maximum orthogonalization residual = 4.58759
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177 | Minimum orthogonalization residual = 0.0335649
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178 | Total integration points = 4049
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179 | Integrated electron density error = -0.000010911185
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180 | iter 1 energy = -38.5282423856 delta = 1.76777e-01
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181 | Total integration points = 24639
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182 | Integrated electron density error = -0.000000836653
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183 | iter 2 energy = -38.5317208606 delta = 6.52896e-03
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184 | Total integration points = 24639
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185 | Integrated electron density error = -0.000000832185
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186 | iter 3 energy = -38.5318574787 delta = 1.78658e-03
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187 | Total integration points = 46071
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188 | Integrated electron density error = -0.000000030156
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189 | iter 4 energy = -38.5318687703 delta = 3.99571e-04
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190 | Total integration points = 46071
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191 | Integrated electron density error = -0.000000030183
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192 | iter 5 energy = -38.5318696691 delta = 1.17999e-04
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193 | Total integration points = 46071
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194 | Integrated electron density error = -0.000000030195
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195 | iter 6 energy = -38.5318697536 delta = 4.07381e-05
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196 | Total integration points = 46071
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197 | Integrated electron density error = -0.000000030068
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198 | iter 7 energy = -38.5318697600 delta = 1.34713e-05
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199 | Total integration points = 46071
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200 | Integrated electron density error = -0.000000030069
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201 | iter 8 energy = -38.5318697604 delta = 3.96862e-06
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202 | Total integration points = 46071
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203 | Integrated electron density error = -0.000000030066
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204 | iter 9 energy = -38.5318697605 delta = 1.08771e-06
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205 |
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206 | HOMO is 1 B1 = -0.097908
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207 | LUMO is 4 A1 = 0.130376
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208 |
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209 | total scf energy = -38.5318697605
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210 |
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211 | SCF::compute: gradient accuracy = 5.7011379e-05
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212 |
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213 | Initializing ShellExtent
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214 | nshell = 8
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215 | ncell = 30690
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216 | ave nsh/cell = 1.82007
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217 | max nsh/cell = 8
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218 | Total integration points = 46071
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219 | Integrated electron density error = -0.000000054247
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220 | Total Gradient:
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221 | 1 C 0.0000000000 0.0000000002 -0.0288879971
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222 | 2 H 0.0000000000 -0.0045634749 0.0144439986
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223 | 3 H -0.0000000000 0.0045634748 0.0144439985
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224 |
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225 | Max Gradient : 0.0288879971 0.0001000000 no
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226 | Max Displacement : 0.1417635129 0.0001000000 no
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227 | Gradient*Displace: 0.0069914501 0.0001000000 no
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228 |
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229 | taking step of size 0.224198
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230 |
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231 | HSOSKS: changing atomic coordinates:
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232 | Molecular formula: CH2
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233 | molecule<Molecule>: (
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234 | symmetry = c2v
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235 | unit = "angstrom"
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236 | { n atoms geometry }={
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237 | 1 C [ 0.0000000000 0.0000000000 0.0416106502]
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238 | 2 H [ -0.0000000000 0.9840460147 0.5250526076]
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239 | 3 H [ -0.0000000000 -0.9840460147 0.5250526076]
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240 | }
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241 | )
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242 | Atomic Masses:
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243 | 12.00000 1.00783 1.00783
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244 |
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245 | SCF::compute: energy accuracy = 2.3867530e-07
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246 |
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247 | Initializing ShellExtent
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248 | nshell = 8
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249 | ncell = 30690
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250 | ave nsh/cell = 1.81821
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251 | max nsh/cell = 8
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252 | nuclear repulsion energy = 6.0607489304
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253 |
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254 | Using symmetric orthogonalization.
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255 | n(SO): 10 1 3 5
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256 | Maximum orthogonalization residual = 4.58057
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257 | Minimum orthogonalization residual = 0.0362942
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258 | Total integration points = 4049
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259 | Integrated electron density error = -0.000028828767
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260 | iter 1 energy = -38.5322198566 delta = 1.77062e-01
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261 | Total integration points = 24639
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262 | Integrated electron density error = 0.000000133410
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263 | iter 2 energy = -38.5357794258 delta = 7.97244e-03
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264 | Total integration points = 24639
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265 | Integrated electron density error = 0.000000141430
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266 | iter 3 energy = -38.5359200204 delta = 1.92818e-03
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267 | Total integration points = 46071
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268 | Integrated electron density error = 0.000000045638
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269 | iter 4 energy = -38.5359371702 delta = 4.43707e-04
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270 | Total integration points = 46071
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271 | Integrated electron density error = 0.000000045641
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272 | iter 5 energy = -38.5359381952 delta = 7.72486e-05
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273 | Total integration points = 46071
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274 | Integrated electron density error = 0.000000045795
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275 | iter 6 energy = -38.5359382992 delta = 3.72320e-05
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276 | Total integration points = 46071
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277 | Integrated electron density error = 0.000000045795
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278 | iter 7 energy = -38.5359383046 delta = 1.09934e-05
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279 | Total integration points = 46071
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280 | Integrated electron density error = 0.000000045802
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281 | iter 8 energy = -38.5359383048 delta = 2.64930e-06
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282 | Total integration points = 46071
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283 | Integrated electron density error = 0.000000045802
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284 | iter 9 energy = -38.5359383048 delta = 7.58056e-07
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285 | Total integration points = 46071
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286 | Integrated electron density error = 0.000000045803
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287 | iter 10 energy = -38.5359383048 delta = 2.39913e-07
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288 |
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289 | HOMO is 1 B1 = -0.097476
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290 | LUMO is 4 A1 = 0.123691
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291 |
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292 | total scf energy = -38.5359383048
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293 |
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294 | SCF::compute: gradient accuracy = 2.3867530e-05
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295 |
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296 | Initializing ShellExtent
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297 | nshell = 8
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298 | ncell = 30690
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299 | ave nsh/cell = 1.81821
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300 | max nsh/cell = 8
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301 | Total integration points = 46071
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302 | Integrated electron density error = 0.000000046438
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303 | Total Gradient:
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304 | 1 C -0.0000000000 -0.0000000000 -0.0050045414
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305 | 2 H 0.0000000000 -0.0019253026 0.0025022707
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306 | 3 H 0.0000000000 0.0019253026 0.0025022707
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307 |
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308 | Max Gradient : 0.0050045414 0.0001000000 no
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309 | Max Displacement : 0.0358887243 0.0001000000 no
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310 | Gradient*Displace: 0.0003651843 0.0001000000 no
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311 |
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312 | taking step of size 0.057257
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313 |
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314 | HSOSKS: changing atomic coordinates:
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315 | Molecular formula: CH2
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316 | molecule<Molecule>: (
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317 | symmetry = c2v
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318 | unit = "angstrom"
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319 | { n atoms geometry }={
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320 | 1 C [ 0.0000000000 0.0000000000 0.0606021465]
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321 | 2 H [ -0.0000000000 0.9972080001 0.5155568594]
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322 | 3 H [ -0.0000000000 -0.9972080001 0.5155568594]
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323 | }
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324 | )
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325 | Atomic Masses:
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326 | 12.00000 1.00783 1.00783
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327 |
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328 | SCF::compute: energy accuracy = 6.0053408e-08
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329 |
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330 | Initializing ShellExtent
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331 | nshell = 8
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332 | ncell = 31620
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333 | ave nsh/cell = 1.76486
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334 | max nsh/cell = 8
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335 | nuclear repulsion energy = 6.0587789191
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336 |
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337 | Using symmetric orthogonalization.
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338 | n(SO): 10 1 3 5
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339 | Maximum orthogonalization residual = 4.57428
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340 | Minimum orthogonalization residual = 0.0371539
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341 | Total integration points = 4049
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342 | Integrated electron density error = -0.000041580388
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343 | iter 1 energy = -38.5358809476 delta = 1.76081e-01
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344 | Total integration points = 24639
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345 | Integrated electron density error = 0.000000358813
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346 | iter 2 energy = -38.5361419458 delta = 1.85249e-03
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347 | Total integration points = 24639
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348 | Integrated electron density error = 0.000000362983
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349 | iter 3 energy = -38.5361520073 delta = 5.18415e-04
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350 | Total integration points = 46071
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351 | Integrated electron density error = 0.000000025746
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352 | iter 4 energy = -38.5361513927 delta = 1.00599e-04
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353 | Total integration points = 46071
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354 | Integrated electron density error = 0.000000025747
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355 | iter 5 energy = -38.5361514707 delta = 2.55320e-05
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356 | Total integration points = 46071
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357 | Integrated electron density error = 0.000000025747
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358 | iter 6 energy = -38.5361514802 delta = 1.19656e-05
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359 | Total integration points = 46071
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360 | Integrated electron density error = 0.000000025756
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361 | iter 7 energy = -38.5361514806 delta = 3.35686e-06
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362 | Total integration points = 46071
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363 | Integrated electron density error = 0.000000025756
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364 | iter 8 energy = -38.5361514806 delta = 8.99811e-07
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365 | Total integration points = 46071
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366 | Integrated electron density error = 0.000000025757
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367 | iter 9 energy = -38.5361514806 delta = 2.26155e-07
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368 | Total integration points = 46071
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369 | Integrated electron density error = 0.000000025757
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370 | iter 10 energy = -38.5361514806 delta = 7.30120e-08
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371 |
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372 | HOMO is 1 B1 = -0.097365
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373 | LUMO is 4 A1 = 0.120447
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374 |
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375 | total scf energy = -38.5361514806
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376 |
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377 | SCF::compute: gradient accuracy = 6.0053408e-06
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378 |
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379 | Initializing ShellExtent
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380 | nshell = 8
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381 | ncell = 31620
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382 | ave nsh/cell = 1.76486
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383 | max nsh/cell = 8
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384 | Total integration points = 46071
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385 | Integrated electron density error = 0.000000024448
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386 | Total Gradient:
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387 | 1 C -0.0000000000 -0.0000000000 -0.0009657547
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388 | 2 H 0.0000000000 -0.0002583652 0.0004828774
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389 | 3 H 0.0000000000 0.0002583652 0.0004828774
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390 |
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391 | Max Gradient : 0.0009657547 0.0001000000 no
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392 | Max Displacement : 0.0078829238 0.0001000000 no
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393 | Gradient*Displace: 0.0000139565 0.0001000000 yes
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394 |
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395 | taking step of size 0.012371
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396 |
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397 | HSOSKS: changing atomic coordinates:
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398 | Molecular formula: CH2
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399 | molecule<Molecule>: (
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400 | symmetry = c2v
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401 | unit = "angstrom"
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402 | { n atoms geometry }={
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403 | 1 C [ 0.0000000000 0.0000000000 0.0647736105]
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404 | 2 H [ -0.0000000000 0.9998062061 0.5134711274]
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405 | 3 H [ -0.0000000000 -0.9998062061 0.5134711274]
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406 | }
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407 | )
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408 | Atomic Masses:
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409 | 12.00000 1.00783 1.00783
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410 |
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411 | SCF::compute: energy accuracy = 1.0071805e-08
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412 |
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413 | Initializing ShellExtent
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414 | nshell = 8
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415 | ncell = 31620
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416 | ave nsh/cell = 1.76448
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417 | max nsh/cell = 8
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418 | nuclear repulsion energy = 6.0592125241
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419 |
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420 | Using symmetric orthogonalization.
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421 | n(SO): 10 1 3 5
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422 | Maximum orthogonalization residual = 4.57329
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423 | Minimum orthogonalization residual = 0.0373196
|
---|
424 | Total integration points = 4049
|
---|
425 | Integrated electron density error = -0.000044993051
|
---|
426 | iter 1 energy = -38.5361396692 delta = 1.75892e-01
|
---|
427 | Total integration points = 46071
|
---|
428 | Integrated electron density error = 0.000000018983
|
---|
429 | iter 2 energy = -38.5361583013 delta = 4.22165e-04
|
---|
430 | Total integration points = 46071
|
---|
431 | Integrated electron density error = 0.000000018992
|
---|
432 | iter 3 energy = -38.5361587993 delta = 1.14439e-04
|
---|
433 | Total integration points = 46071
|
---|
434 | Integrated electron density error = 0.000000019091
|
---|
435 | iter 4 energy = -38.5361588455 delta = 2.30265e-05
|
---|
436 | Total integration points = 46071
|
---|
437 | Integrated electron density error = 0.000000019092
|
---|
438 | iter 5 energy = -38.5361588496 delta = 5.69303e-06
|
---|
439 | Total integration points = 46071
|
---|
440 | Integrated electron density error = 0.000000019092
|
---|
441 | iter 6 energy = -38.5361588500 delta = 2.72964e-06
|
---|
442 | Total integration points = 46071
|
---|
443 | Integrated electron density error = 0.000000019099
|
---|
444 | iter 7 energy = -38.5361588501 delta = 7.19341e-07
|
---|
445 | Total integration points = 46071
|
---|
446 | Integrated electron density error = 0.000000019099
|
---|
447 | iter 8 energy = -38.5361588501 delta = 1.96045e-07
|
---|
448 | Total integration points = 46071
|
---|
449 | Integrated electron density error = 0.000000019099
|
---|
450 | iter 9 energy = -38.5361588501 delta = 4.66264e-08
|
---|
451 | Total integration points = 46071
|
---|
452 | Integrated electron density error = 0.000000019099
|
---|
453 | iter 10 energy = -38.5361588501 delta = 1.50178e-08
|
---|
454 |
|
---|
455 | HOMO is 1 B1 = -0.097344
|
---|
456 | LUMO is 4 A1 = 0.119777
|
---|
457 |
|
---|
458 | total scf energy = -38.5361588501
|
---|
459 |
|
---|
460 | SCF::compute: gradient accuracy = 1.0071805e-06
|
---|
461 |
|
---|
462 | Initializing ShellExtent
|
---|
463 | nshell = 8
|
---|
464 | ncell = 31620
|
---|
465 | ave nsh/cell = 1.76448
|
---|
466 | max nsh/cell = 8
|
---|
467 | Total integration points = 46071
|
---|
468 | Integrated electron density error = 0.000000018826
|
---|
469 | Total Gradient:
|
---|
470 | 1 C -0.0000000000 -0.0000000000 -0.0000549214
|
---|
471 | 2 H -0.0000000000 -0.0000181473 0.0000274607
|
---|
472 | 3 H 0.0000000000 0.0000181473 0.0000274607
|
---|
473 |
|
---|
474 | Max Gradient : 0.0000549214 0.0001000000 yes
|
---|
475 | Max Displacement : 0.0004937464 0.0001000000 no
|
---|
476 | Gradient*Displace: 0.0000000521 0.0001000000 yes
|
---|
477 |
|
---|
478 | taking step of size 0.000778
|
---|
479 |
|
---|
480 | HSOSKS: changing atomic coordinates:
|
---|
481 | Molecular formula: CH2
|
---|
482 | molecule<Molecule>: (
|
---|
483 | symmetry = c2v
|
---|
484 | unit = "angstrom"
|
---|
485 | { n atoms geometry }={
|
---|
486 | 1 C [ 0.0000000000 0.0000000000 0.0650348898]
|
---|
487 | 2 H [ -0.0000000000 0.9999734177 0.5133404877]
|
---|
488 | 3 H [ -0.0000000000 -0.9999734177 0.5133404877]
|
---|
489 | }
|
---|
490 | )
|
---|
491 | Atomic Masses:
|
---|
492 | 12.00000 1.00783 1.00783
|
---|
493 |
|
---|
494 | SCF::compute: energy accuracy = 6.2132775e-10
|
---|
495 |
|
---|
496 | Initializing ShellExtent
|
---|
497 | nshell = 8
|
---|
498 | ncell = 31620
|
---|
499 | ave nsh/cell = 1.76452
|
---|
500 | max nsh/cell = 8
|
---|
501 | nuclear repulsion energy = 6.0592096862
|
---|
502 |
|
---|
503 | Using symmetric orthogonalization.
|
---|
504 | n(SO): 10 1 3 5
|
---|
505 | Maximum orthogonalization residual = 4.57321
|
---|
506 | Minimum orthogonalization residual = 0.0373303
|
---|
507 | Total integration points = 4049
|
---|
508 | Integrated electron density error = -0.000045340262
|
---|
509 | iter 1 energy = -38.5361523540 delta = 1.75843e-01
|
---|
510 | Total integration points = 46071
|
---|
511 | Integrated electron density error = 0.000000018656
|
---|
512 | iter 2 energy = -38.5361588725 delta = 2.85386e-05
|
---|
513 | Total integration points = 46071
|
---|
514 | Integrated electron density error = 0.000000018655
|
---|
515 | iter 3 energy = -38.5361588760 delta = 6.53577e-06
|
---|
516 | Total integration points = 46071
|
---|
517 | Integrated electron density error = 0.000000018663
|
---|
518 | iter 4 energy = -38.5361588764 delta = 2.63330e-06
|
---|
519 | Total integration points = 46071
|
---|
520 | Integrated electron density error = 0.000000018663
|
---|
521 | iter 5 energy = -38.5361588764 delta = 8.13867e-07
|
---|
522 | Total integration points = 46071
|
---|
523 | Integrated electron density error = 0.000000018664
|
---|
524 | iter 6 energy = -38.5361588764 delta = 1.98645e-07
|
---|
525 | Total integration points = 46071
|
---|
526 | Integrated electron density error = 0.000000018664
|
---|
527 | iter 7 energy = -38.5361588764 delta = 4.74905e-08
|
---|
528 | Total integration points = 46071
|
---|
529 | Integrated electron density error = 0.000000018664
|
---|
530 | iter 8 energy = -38.5361588764 delta = 1.51033e-08
|
---|
531 | Total integration points = 46071
|
---|
532 | Integrated electron density error = 0.000000018664
|
---|
533 | iter 9 energy = -38.5361588764 delta = 3.72306e-09
|
---|
534 | Total integration points = 46071
|
---|
535 | Integrated electron density error = 0.000000018664
|
---|
536 | iter 10 energy = -38.5361588764 delta = 9.81674e-10
|
---|
537 |
|
---|
538 | HOMO is 1 B1 = -0.097343
|
---|
539 | LUMO is 4 A1 = 0.119732
|
---|
540 |
|
---|
541 | total scf energy = -38.5361588764
|
---|
542 |
|
---|
543 | SCF::compute: gradient accuracy = 6.2132775e-08
|
---|
544 |
|
---|
545 | Initializing ShellExtent
|
---|
546 | nshell = 8
|
---|
547 | ncell = 31620
|
---|
548 | ave nsh/cell = 1.76452
|
---|
549 | max nsh/cell = 8
|
---|
550 | Total integration points = 46071
|
---|
551 | Integrated electron density error = 0.000000018651
|
---|
552 | Total Gradient:
|
---|
553 | 1 C 0.0000000000 0.0000000000 -0.0000008269
|
---|
554 | 2 H -0.0000000000 -0.0000000322 0.0000004134
|
---|
555 | 3 H -0.0000000000 0.0000000322 0.0000004134
|
---|
556 |
|
---|
557 | Max Gradient : 0.0000008269 0.0001000000 yes
|
---|
558 | Max Displacement : 0.0000063017 0.0001000000 yes
|
---|
559 | Gradient*Displace: 0.0000000000 0.0001000000 yes
|
---|
560 |
|
---|
561 | All convergence criteria have been met.
|
---|
562 | The optimization has converged.
|
---|
563 |
|
---|
564 | Value of the MolecularEnergy: -38.5361588764
|
---|
565 |
|
---|
566 | Restricted Open Shell Kohn-Sham (HSOSKS) Parameters:
|
---|
567 | Function Parameters:
|
---|
568 | value_accuracy = 3.163323e-10 (6.213278e-10) (computed)
|
---|
569 | gradient_accuracy = 3.163323e-08 (6.213278e-08) (computed)
|
---|
570 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
|
---|
571 |
|
---|
572 | Molecular Coordinates:
|
---|
573 | IntMolecularCoor Parameters:
|
---|
574 | update_bmat = no
|
---|
575 | scale_bonds = 1
|
---|
576 | scale_bends = 1
|
---|
577 | scale_tors = 1
|
---|
578 | scale_outs = 1
|
---|
579 | symmetry_tolerance = 1.000000e-05
|
---|
580 | simple_tolerance = 1.000000e-03
|
---|
581 | coordinate_tolerance = 1.000000e-07
|
---|
582 | have_fixed_values = 0
|
---|
583 | max_update_steps = 100
|
---|
584 | max_update_disp = 0.500000
|
---|
585 | have_fixed_values = 0
|
---|
586 |
|
---|
587 | Molecular formula: CH2
|
---|
588 | molecule<Molecule>: (
|
---|
589 | symmetry = c2v
|
---|
590 | unit = "angstrom"
|
---|
591 | { n atoms geometry }={
|
---|
592 | 1 C [ 0.0000000000 0.0000000000 0.0650348898]
|
---|
593 | 2 H [ -0.0000000000 0.9999734177 0.5133404877]
|
---|
594 | 3 H [ -0.0000000000 -0.9999734177 0.5133404877]
|
---|
595 | }
|
---|
596 | )
|
---|
597 | Atomic Masses:
|
---|
598 | 12.00000 1.00783 1.00783
|
---|
599 |
|
---|
600 | Bonds:
|
---|
601 | STRE s1 1.09587 1 2 C-H
|
---|
602 | STRE s2 1.09587 1 3 C-H
|
---|
603 | Bends:
|
---|
604 | BEND b1 131.70494 2 1 3 H-C-H
|
---|
605 |
|
---|
606 | SymmMolecularCoor Parameters:
|
---|
607 | change_coordinates = no
|
---|
608 | transform_hessian = yes
|
---|
609 | max_kappa2 = 10.000000
|
---|
610 |
|
---|
611 | GaussianBasisSet:
|
---|
612 | nbasis = 19
|
---|
613 | nshell = 8
|
---|
614 | nprim = 19
|
---|
615 | name = "6-31G*"
|
---|
616 | Natural Population Analysis:
|
---|
617 | n atom charge ne(S) ne(P) ne(D)
|
---|
618 | 1 C -0.287845 3.303263 2.981637 0.002945
|
---|
619 | 2 H 0.143923 0.856077
|
---|
620 | 3 H 0.143923 0.856077
|
---|
621 |
|
---|
622 | SCF Parameters:
|
---|
623 | maxiter = 100
|
---|
624 | density_reset_frequency = 10
|
---|
625 | level_shift = 0.250000
|
---|
626 |
|
---|
627 | HSOSSCF Parameters:
|
---|
628 | charge = 0
|
---|
629 | ndocc = 3
|
---|
630 | nsocc = 2
|
---|
631 | docc = [ 2 0 0 1 ]
|
---|
632 | socc = [ 1 0 1 0 ]
|
---|
633 |
|
---|
634 | Functional:
|
---|
635 | Standard Density Functional: XALPHA
|
---|
636 | Sum of Functionals:
|
---|
637 | +1.0000000000000000
|
---|
638 | XalphaFunctional: alpha = 0.70000000
|
---|
639 | Integrator:
|
---|
640 | RadialAngularIntegrator:
|
---|
641 | Pruned fine grid employed
|
---|
642 | CPU Wall
|
---|
643 | mpqc: 30.56 33.67
|
---|
644 | NAO: 0.02 0.02
|
---|
645 | calc: 30.31 33.42
|
---|
646 | compute gradient: 8.30 9.50
|
---|
647 | nuc rep: 0.00 0.00
|
---|
648 | one electron gradient: 0.11 0.09
|
---|
649 | overlap gradient: 0.03 0.04
|
---|
650 | two electron gradient: 8.16 9.37
|
---|
651 | grad: 8.16 9.37
|
---|
652 | integrate: 6.66 7.86
|
---|
653 | two-body: 0.52 0.55
|
---|
654 | vector: 22.01 23.88
|
---|
655 | density: 0.01 0.04
|
---|
656 | evals: 0.08 0.08
|
---|
657 | extrap: 0.11 0.14
|
---|
658 | fock: 20.67 22.54
|
---|
659 | integrate: 19.16 21.06
|
---|
660 | start thread: 0.15 0.17
|
---|
661 | stop thread: 0.00 0.01
|
---|
662 | input: 0.23 0.23
|
---|
663 | vector: 0.09 0.09
|
---|
664 | density: 0.01 0.00
|
---|
665 | evals: 0.00 0.01
|
---|
666 | extrap: 0.02 0.01
|
---|
667 | fock: 0.04 0.05
|
---|
668 | start thread: 0.00 0.00
|
---|
669 | stop thread: 0.00 0.00
|
---|
670 |
|
---|
671 | End Time: Sat Apr 6 14:01:37 2002
|
---|
672 |
|
---|