1 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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2 |
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3 | MPQC: Massively Parallel Quantum Chemistry
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4 | Version 2.1.0-alpha-gcc3
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5 |
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6 | Machine: i686-pc-linux-gnu
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7 | User: cljanss@aros.ca.sandia.gov
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8 | Start Time: Sat Apr 6 14:00:26 2002
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9 |
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10 | Using ProcMessageGrp for message passing (number of nodes = 1).
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11 | Using PthreadThreadGrp for threading (number of threads = 2).
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12 | Using ProcMemoryGrp for distributed shared memory.
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13 | Total number of processors = 2
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14 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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15 | Molecule: setting point group to c2v
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16 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/6-31gS.kv.
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17 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
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18 |
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19 | CLSCF::init: total charge = 0
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20 |
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21 | Starting from core Hamiltonian guess
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22 |
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23 | Using symmetric orthogonalization.
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24 | n(SO): 4 0 1 2
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25 | Maximum orthogonalization residual = 1.94039
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26 | Minimum orthogonalization residual = 0.335627
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27 | docc = [ 3 0 1 1 ]
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28 | nbasis = 7
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29 |
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30 | CLSCF::init: total charge = 0
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31 |
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32 | Projecting guess wavefunction into the present basis set
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33 |
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34 | SCF::compute: energy accuracy = 1.0000000e-06
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35 |
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36 | integral intermediate storage = 31876 bytes
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37 | integral cache = 7967676 bytes
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38 | nuclear repulsion energy = 9.2914265473
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39 |
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40 | 565 integrals
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41 | iter 1 energy = -74.6442059283 delta = 7.46913e-01
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42 | 565 integrals
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43 | iter 2 energy = -74.9411785471 delta = 2.32701e-01
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44 | 565 integrals
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45 | iter 3 energy = -74.9598835707 delta = 6.74768e-02
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46 | 565 integrals
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47 | iter 4 energy = -74.9608017389 delta = 1.82839e-02
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48 | 565 integrals
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49 | iter 5 energy = -74.9608457808 delta = 4.27179e-03
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50 | 565 integrals
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51 | iter 6 energy = -74.9608460189 delta = 2.87494e-04
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52 | 565 integrals
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53 | iter 7 energy = -74.9608460194 delta = 1.50392e-05
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54 |
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55 | HOMO is 1 B1 = -0.391179
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56 | LUMO is 4 A1 = 0.614055
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57 |
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58 | total scf energy = -74.9608460194
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59 |
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60 | Projecting the guess density.
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61 |
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62 | The number of electrons in the guess density = 10
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63 | Using symmetric orthogonalization.
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64 | n(SO): 10 1 3 5
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65 | Maximum orthogonalization residual = 4.69613
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66 | Minimum orthogonalization residual = 0.0219193
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67 | The number of electrons in the projected density = 9.95801
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68 |
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69 | docc = [ 3 0 1 1 ]
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70 | nbasis = 19
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71 |
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72 | Molecular formula H2O
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73 |
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74 | MPQC options:
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75 | matrixkit = <ReplSCMatrixKit>
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76 | filename = input_hfh2ofreq
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77 | restart_file = input_hfh2ofreq.ckpt
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78 | restart = no
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79 | checkpoint = no
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80 | savestate = no
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81 | do_energy = yes
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82 | do_gradient = no
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83 | optimize = no
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84 | write_pdb = no
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85 | print_mole = yes
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86 | print_timings = yes
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87 |
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88 | SCF::compute: energy accuracy = 1.0000000e-06
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89 |
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90 | integral intermediate storage = 236328 bytes
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91 | integral cache = 7760632 bytes
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92 | nuclear repulsion energy = 9.2914265473
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93 |
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94 | 19108 integrals
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95 | iter 1 energy = -75.8313984939 delta = 2.12979e-01
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96 | 19108 integrals
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97 | iter 2 energy = -75.9893342668 delta = 5.77199e-02
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98 | 19108 integrals
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99 | iter 3 energy = -76.0061172655 delta = 1.48537e-02
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100 | 19108 integrals
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101 | iter 4 energy = -76.0104307742 delta = 6.83190e-03
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102 | 19108 integrals
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103 | iter 5 energy = -76.0107349333 delta = 2.29768e-03
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104 | 19108 integrals
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105 | iter 6 energy = -76.0107461220 delta = 5.11193e-04
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106 | 19108 integrals
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107 | iter 7 energy = -76.0107462842 delta = 5.25319e-05
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108 | 19108 integrals
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109 | iter 8 energy = -76.0107462976 delta = 1.68043e-05
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110 | 19108 integrals
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111 | iter 9 energy = -76.0107462983 delta = 4.02927e-06
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112 | 19108 integrals
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113 | iter 10 energy = -76.0107462984 delta = 1.15008e-06
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114 |
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115 | HOMO is 1 B1 = -0.498217
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116 | LUMO is 4 A1 = 0.213089
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117 |
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118 | total scf energy = -76.0107462984
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119 |
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120 | Value of the MolecularEnergy: -76.0107462984
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121 |
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122 | The external rank is 6
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123 | Computing molecular hessian from 6 displacements:
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124 | Starting at displacement: 0
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125 | Hessian options:
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126 | displacement: 0.01 bohr
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127 | gradient_accuracy: 1e-05 au
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128 | eliminate_cubic_terms: yes
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129 | only_totally_symmetric: no
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130 |
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131 | Beginning displacement 0:
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132 | Molecule: setting point group to c2v
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133 | Displacement is A1 in c2v. Using point group c2v for displaced molecule.
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134 |
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135 | SCF::compute: energy accuracy = 1.0000000e-07
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136 |
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137 | integral intermediate storage = 236328 bytes
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138 | integral cache = 7760632 bytes
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139 | nuclear repulsion energy = 9.2914265473
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140 |
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141 | Using symmetric orthogonalization.
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142 | n(SO): 10 1 3 5
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143 | Maximum orthogonalization residual = 4.69613
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144 | Minimum orthogonalization residual = 0.0219193
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145 | 19108 integrals
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146 | iter 1 energy = -76.0107462984 delta = 2.09895e-01
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147 | 19108 integrals
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148 | iter 2 energy = -76.0107462984 delta = 1.86331e-08
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149 |
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150 | HOMO is 1 B1 = -0.498218
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151 | LUMO is 4 A1 = 0.213089
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152 |
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153 | total scf energy = -76.0107462984
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154 |
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155 | SCF::compute: gradient accuracy = 1.0000000e-05
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156 |
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157 | Total Gradient:
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158 | 1 O 0.0004691490 0.0000000000 0.0000000000
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159 | 2 H -0.0002345745 -0.0000000000 -0.0002321324
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160 | 3 H -0.0002345745 -0.0000000000 0.0002321324
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161 |
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162 | Beginning displacement 1:
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163 | Molecule: setting point group to c2v
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164 | Displacement is A1 in c2v. Using point group c2v for displaced molecule.
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165 |
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166 | SCF::compute: energy accuracy = 1.0000000e-07
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167 |
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168 | integral intermediate storage = 236328 bytes
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169 | integral cache = 7760632 bytes
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170 | nuclear repulsion energy = 9.2713628191
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171 |
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172 | Using symmetric orthogonalization.
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173 | n(SO): 10 1 3 5
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174 | Maximum orthogonalization residual = 4.69009
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175 | Minimum orthogonalization residual = 0.0219947
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176 | 19108 integrals
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177 | iter 1 energy = -76.0107168738 delta = 2.09903e-01
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178 | 19108 integrals
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179 | iter 2 energy = -76.0107327055 delta = 4.41842e-04
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180 | 19108 integrals
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181 | iter 3 energy = -76.0107332524 delta = 9.95819e-05
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182 | 19108 integrals
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183 | iter 4 energy = -76.0107333392 delta = 3.04180e-05
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184 | 19108 integrals
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185 | iter 5 energy = -76.0107333482 delta = 1.06061e-05
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186 | 19108 integrals
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187 | iter 6 energy = -76.0107333492 delta = 4.39723e-06
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188 | 19108 integrals
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189 | iter 7 energy = -76.0107333492 delta = 8.82987e-07
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190 | 19108 integrals
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191 | iter 8 energy = -76.0107333492 delta = 1.73915e-07
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192 |
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193 | HOMO is 1 B1 = -0.497903
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194 | LUMO is 4 A1 = 0.212736
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195 |
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196 | total scf energy = -76.0107333492
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197 |
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198 | SCF::compute: gradient accuracy = 1.0000000e-05
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199 |
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200 | Total Gradient:
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201 | 1 O -0.0010405841 0.0000000000 -0.0000000000
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202 | 2 H 0.0005202920 -0.0000000000 0.0022405305
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203 | 3 H 0.0005202920 -0.0000000000 -0.0022405305
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204 |
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205 | Beginning displacement 2:
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206 | Molecule: setting point group to c2v
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207 | Displacement is A1 in c2v. Using point group c2v for displaced molecule.
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208 |
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209 | SCF::compute: energy accuracy = 1.0000000e-07
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210 |
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211 | integral intermediate storage = 236328 bytes
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212 | integral cache = 7760632 bytes
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213 | nuclear repulsion energy = 9.2483981954
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214 |
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215 | Using symmetric orthogonalization.
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216 | n(SO): 10 1 3 5
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217 | Maximum orthogonalization residual = 4.68748
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218 | Minimum orthogonalization residual = 0.0220808
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219 | 19108 integrals
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220 | iter 1 energy = -76.0106433186 delta = 2.09707e-01
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221 | 19108 integrals
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222 | iter 2 energy = -76.0106998497 delta = 1.24263e-03
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223 | 19108 integrals
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224 | iter 3 energy = -76.0107037606 delta = 2.93534e-04
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225 | 19108 integrals
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226 | iter 4 energy = -76.0107045194 delta = 1.00100e-04
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227 | 19108 integrals
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228 | iter 5 energy = -76.0107046612 delta = 4.91826e-05
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229 | 19108 integrals
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230 | iter 6 energy = -76.0107046779 delta = 2.31661e-05
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231 | 19108 integrals
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232 | iter 7 energy = -76.0107046780 delta = 1.57454e-06
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233 | 19108 integrals
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234 | iter 8 energy = -76.0107046780 delta = 2.73161e-07
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235 |
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236 | HOMO is 1 B1 = -0.498108
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237 | LUMO is 4 A1 = 0.212038
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238 |
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239 | total scf energy = -76.0107046780
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240 |
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241 | SCF::compute: gradient accuracy = 1.0000000e-05
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242 |
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243 | Total Gradient:
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244 | 1 O -0.0066012454 0.0000000000 0.0000000000
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245 | 2 H 0.0033006227 -0.0000000000 0.0031779831
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246 | 3 H 0.0033006227 -0.0000000000 -0.0031779831
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247 |
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248 | Beginning displacement 3:
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249 | Molecule: setting point group to c2v
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250 | Displacement is A1 in c2v. Using point group c2v for displaced molecule.
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251 |
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252 | SCF::compute: energy accuracy = 1.0000000e-07
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253 |
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254 | integral intermediate storage = 236328 bytes
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255 | integral cache = 7760632 bytes
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256 | nuclear repulsion energy = 9.3114638385
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257 |
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258 | Using symmetric orthogonalization.
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259 | n(SO): 10 1 3 5
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260 | Maximum orthogonalization residual = 4.70216
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261 | Minimum orthogonalization residual = 0.0218448
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262 | 19108 integrals
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263 | iter 1 energy = -76.0106307945 delta = 2.10102e-01
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264 | 19108 integrals
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265 | iter 2 energy = -76.0107221272 delta = 1.46434e-03
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266 | 19108 integrals
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267 | iter 3 energy = -76.0107280713 delta = 3.42812e-04
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268 | 19108 integrals
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269 | iter 4 energy = -76.0107295333 delta = 1.36029e-04
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270 | 19108 integrals
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271 | iter 5 energy = -76.0107296860 delta = 4.54298e-05
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272 | 19108 integrals
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273 | iter 6 energy = -76.0107297039 delta = 2.30328e-05
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274 | 19108 integrals
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275 | iter 7 energy = -76.0107297041 delta = 2.17592e-06
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276 | 19108 integrals
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277 | iter 8 energy = -76.0107297041 delta = 4.74694e-07
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278 |
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279 | HOMO is 1 B1 = -0.498531
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280 | LUMO is 4 A1 = 0.213430
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281 |
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282 | total scf energy = -76.0107297041
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283 |
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284 | SCF::compute: gradient accuracy = 1.0000000e-05
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285 |
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286 | Total Gradient:
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287 | 1 O 0.0020165841 0.0000000000 0.0000000000
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288 | 2 H -0.0010082920 -0.0000000000 -0.0027230783
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289 | 3 H -0.0010082920 -0.0000000000 0.0027230783
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290 |
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291 | Beginning displacement 4:
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292 | Molecule: setting point group to c2v
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293 | Displacement is A1 in c2v. Using point group c2v for displaced molecule.
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294 |
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295 | SCF::compute: energy accuracy = 1.0000000e-07
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296 |
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297 | integral intermediate storage = 236328 bytes
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298 | integral cache = 7760632 bytes
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299 | nuclear repulsion energy = 9.3346656189
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300 |
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301 | Using symmetric orthogonalization.
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302 | n(SO): 10 1 3 5
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303 | Maximum orthogonalization residual = 4.70475
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304 | Minimum orthogonalization residual = 0.0217598
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305 | 19108 integrals
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306 | iter 1 energy = -76.0106278992 delta = 2.10097e-01
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307 | 19108 integrals
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308 | iter 2 energy = -76.0106864378 delta = 1.27390e-03
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309 | 19108 integrals
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310 | iter 3 energy = -76.0106904174 delta = 2.99792e-04
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311 | 19108 integrals
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312 | iter 4 energy = -76.0106911794 delta = 1.00691e-04
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313 | 19108 integrals
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314 | iter 5 energy = -76.0106913183 delta = 4.92094e-05
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315 | 19108 integrals
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316 | iter 6 energy = -76.0106913345 delta = 2.29549e-05
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317 | 19108 integrals
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318 | iter 7 energy = -76.0106913346 delta = 1.58762e-06
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319 | 19108 integrals
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320 | iter 8 energy = -76.0106913346 delta = 2.59742e-07
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321 |
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322 | HOMO is 1 B1 = -0.498334
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323 | LUMO is 4 A1 = 0.214132
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324 |
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325 | total scf energy = -76.0106913346
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326 |
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327 | SCF::compute: gradient accuracy = 1.0000000e-05
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328 |
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329 | Total Gradient:
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330 | 1 O 0.0076545848 0.0000000000 0.0000000000
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331 | 2 H -0.0038272924 -0.0000000000 -0.0037750779
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332 | 3 H -0.0038272924 -0.0000000000 0.0037750779
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333 |
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334 | Beginning displacement 5:
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335 | Molecule: setting point group to cs
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336 | Displacement is B2 in c2v. Using point group cs for displaced molecule.
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337 |
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338 | SCF::compute: energy accuracy = 1.0000000e-07
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339 |
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340 | integral intermediate storage = 236328 bytes
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341 | integral cache = 7760632 bytes
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342 | Projecting guess wavefunction into the present basis set
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343 |
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344 | SCF::compute: energy accuracy = 1.0000000e-06
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345 |
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346 | integral intermediate storage = 31876 bytes
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347 | integral cache = 7967676 bytes
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348 | Starting from core Hamiltonian guess
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349 |
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350 | Using symmetric orthogonalization.
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351 | n(SO): 6 1
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352 | Maximum orthogonalization residual = 1.94042
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353 | Minimum orthogonalization residual = 0.3354
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354 | nuclear repulsion energy = 9.2917138257
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355 |
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356 | 733 integrals
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357 | iter 1 energy = -74.6441111903 delta = 7.46789e-01
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358 | 733 integrals
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359 | iter 2 energy = -74.9410849693 delta = 2.27702e-01
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360 | 733 integrals
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361 | iter 3 energy = -74.9597742006 delta = 6.70496e-02
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362 | 733 integrals
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363 | iter 4 energy = -74.9607071950 delta = 1.85604e-02
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364 | 733 integrals
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365 | iter 5 energy = -74.9607494303 delta = 3.80143e-03
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366 | 733 integrals
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367 | iter 6 energy = -74.9607496841 delta = 2.82464e-04
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368 | 733 integrals
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369 | iter 7 energy = -74.9607496844 delta = 9.74967e-06
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370 |
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371 | HOMO is 1 A" = -0.391187
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372 | LUMO is 5 A' = 0.613805
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373 |
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374 | total scf energy = -74.9607496844
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375 |
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376 | Projecting the guess density.
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377 |
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378 | The number of electrons in the guess density = 10
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379 | Using symmetric orthogonalization.
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380 | n(SO): 15 4
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381 | Maximum orthogonalization residual = 4.69616
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382 | Minimum orthogonalization residual = 0.0219165
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383 | The number of electrons in the projected density = 9.95801
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384 |
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385 | nuclear repulsion energy = 9.2917138257
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386 |
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387 | 25330 integrals
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388 | iter 1 energy = -75.8313073803 delta = 2.12869e-01
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389 | 25330 integrals
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390 | iter 2 energy = -75.9892651359 delta = 5.76207e-02
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391 | 25330 integrals
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392 | iter 3 energy = -76.0060646997 delta = 1.47923e-02
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393 | 25330 integrals
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394 | iter 4 energy = -76.0103608950 delta = 6.82584e-03
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395 | 25330 integrals
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396 | iter 5 energy = -76.0106645434 delta = 2.29496e-03
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397 | 25330 integrals
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398 | iter 6 energy = -76.0106757084 delta = 5.10629e-04
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399 | 25330 integrals
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400 | iter 7 energy = -76.0106758705 delta = 5.24087e-05
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401 | 25330 integrals
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402 | iter 8 energy = -76.0106758838 delta = 1.66862e-05
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403 | 25330 integrals
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404 | iter 9 energy = -76.0106758846 delta = 3.98484e-06
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405 | 25330 integrals
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406 | iter 10 energy = -76.0106758846 delta = 1.13646e-06
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407 | 25330 integrals
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408 | iter 11 energy = -76.0106758846 delta = 1.45371e-07
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409 |
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410 | HOMO is 1 A" = -0.498222
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411 | LUMO is 5 A' = 0.213059
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412 |
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413 | total scf energy = -76.0106758846
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414 |
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415 | SCF::compute: gradient accuracy = 1.0000000e-05
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416 |
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417 | Total Gradient:
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418 | 1 O 0.0006454807 0.0000000000 -0.0105297251
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419 | 2 H 0.0036801738 -0.0000000000 0.0049428248
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420 | 3 H -0.0043256545 -0.0000000000 0.0055869003
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421 | Molecule: setting point group to c2v
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422 | The external rank is 6
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423 |
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424 | Frequencies (cm-1; negative is imaginary):
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425 | A1
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426 | 1 4074.63
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427 | 2 1825.22
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428 |
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429 | B2
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430 | 3 4193.34
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431 |
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432 | THERMODYNAMIC ANALYSIS:
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433 |
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434 | Contributions to the nonelectronic enthalpy at 298.15 K:
|
---|
435 | kJ/mol kcal/mol
|
---|
436 | E0vib = 60.3707 14.4289
|
---|
437 | Evib(T) = 0.0033 0.0008
|
---|
438 | Erot(T) = 3.7185 0.8887
|
---|
439 | Etrans(T) = 3.7185 0.8887
|
---|
440 | PV(T) = 2.4790 0.5925
|
---|
441 | Total nonelectronic enthalpy:
|
---|
442 | H_nonel(T) = 70.2899 16.7997
|
---|
443 |
|
---|
444 | Contributions to the entropy at 298.15 K and 1.0 atm:
|
---|
445 | J/(mol*K) cal/(mol*K)
|
---|
446 | S_trans(T,P) = 144.8020 34.6085
|
---|
447 | S_rot(T) = 43.4035 10.3737
|
---|
448 | S_vib(T) = 0.0122 0.0029
|
---|
449 | S_el = 0.0000 0.0000
|
---|
450 | Total entropy:
|
---|
451 | S_total(T,P) = 188.2176 44.9851
|
---|
452 |
|
---|
453 | Various data used for thermodynamic analysis:
|
---|
454 |
|
---|
455 | Nonlinear molecule
|
---|
456 | Principal moments of inertia (amu*angstrom^2): 0.58773, 1.14593, 1.73366
|
---|
457 | Point group: c2v
|
---|
458 | Order of point group: 4
|
---|
459 | Rotational symmetry number: 2
|
---|
460 | Rotational temperatures (K): 41.2676, 21.1656, 13.9902
|
---|
461 | Electronic degeneracy: 1
|
---|
462 |
|
---|
463 | Function Parameters:
|
---|
464 | value_accuracy = 2.772912e-08 (1.000000e-07)
|
---|
465 | gradient_accuracy = 2.772912e-06 (1.000000e-06)
|
---|
466 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
|
---|
467 |
|
---|
468 | Molecule:
|
---|
469 | Molecular formula: H2O
|
---|
470 | molecule<Molecule>: (
|
---|
471 | symmetry = c2v
|
---|
472 | symmetry_frame = [
|
---|
473 | [ -0.0000000000000000 0.0000000000000000 1.0000000000000000]
|
---|
474 | [ 1.0000000000000000 0.0000000000000000 -0.0000000000000000]
|
---|
475 | [ -0.0000000000000000 1.0000000000000000 -0.0000000000000000]]
|
---|
476 | unit = "angstrom"
|
---|
477 | { n atoms geometry }={
|
---|
478 | 1 O [ -0.0641272226 0.0000000000 0.0000000000]
|
---|
479 | 2 H [ 0.5088727774 -0.0000000000 0.7540000000]
|
---|
480 | 3 H [ 0.5088727774 -0.0000000000 -0.7540000000]
|
---|
481 | }
|
---|
482 | )
|
---|
483 | Atomic Masses:
|
---|
484 | 15.99491 1.00783 1.00783
|
---|
485 |
|
---|
486 | GaussianBasisSet:
|
---|
487 | nbasis = 19
|
---|
488 | nshell = 8
|
---|
489 | nprim = 19
|
---|
490 | name = "6-31G*"
|
---|
491 |
|
---|
492 | SCF::compute: energy accuracy = 1.0000000e-07
|
---|
493 |
|
---|
494 | integral intermediate storage = 236328 bytes
|
---|
495 | integral cache = 7760632 bytes
|
---|
496 | Projecting guess wavefunction into the present basis set
|
---|
497 |
|
---|
498 | SCF::compute: energy accuracy = 1.0000000e-06
|
---|
499 |
|
---|
500 | integral intermediate storage = 31876 bytes
|
---|
501 | integral cache = 7967676 bytes
|
---|
502 | Starting from core Hamiltonian guess
|
---|
503 |
|
---|
504 | Using symmetric orthogonalization.
|
---|
505 | n(SO): 4 0 1 2
|
---|
506 | Maximum orthogonalization residual = 1.94039
|
---|
507 | Minimum orthogonalization residual = 0.335627
|
---|
508 | nuclear repulsion energy = 9.2914265473
|
---|
509 |
|
---|
510 | 565 integrals
|
---|
511 | iter 1 energy = -74.6442059283 delta = 7.46913e-01
|
---|
512 | 565 integrals
|
---|
513 | iter 2 energy = -74.9411785471 delta = 2.32701e-01
|
---|
514 | 565 integrals
|
---|
515 | iter 3 energy = -74.9598835707 delta = 6.74768e-02
|
---|
516 | 565 integrals
|
---|
517 | iter 4 energy = -74.9608017389 delta = 1.82839e-02
|
---|
518 | 565 integrals
|
---|
519 | iter 5 energy = -74.9608457808 delta = 4.27179e-03
|
---|
520 | 565 integrals
|
---|
521 | iter 6 energy = -74.9608460189 delta = 2.87494e-04
|
---|
522 | 565 integrals
|
---|
523 | iter 7 energy = -74.9608460194 delta = 1.50392e-05
|
---|
524 |
|
---|
525 | HOMO is 1 B1 = -0.391179
|
---|
526 | LUMO is 4 A1 = 0.614055
|
---|
527 |
|
---|
528 | total scf energy = -74.9608460194
|
---|
529 |
|
---|
530 | Projecting the guess density.
|
---|
531 |
|
---|
532 | The number of electrons in the guess density = 10
|
---|
533 | Using symmetric orthogonalization.
|
---|
534 | n(SO): 10 1 3 5
|
---|
535 | Maximum orthogonalization residual = 4.69613
|
---|
536 | Minimum orthogonalization residual = 0.0219193
|
---|
537 | The number of electrons in the projected density = 9.95801
|
---|
538 |
|
---|
539 | nuclear repulsion energy = 9.2914265473
|
---|
540 |
|
---|
541 | 19108 integrals
|
---|
542 | iter 1 energy = -75.8313984939 delta = 2.12979e-01
|
---|
543 | 19108 integrals
|
---|
544 | iter 2 energy = -75.9893342668 delta = 5.77199e-02
|
---|
545 | 19108 integrals
|
---|
546 | iter 3 energy = -76.0061172655 delta = 1.48537e-02
|
---|
547 | 19108 integrals
|
---|
548 | iter 4 energy = -76.0104307742 delta = 6.83190e-03
|
---|
549 | 19108 integrals
|
---|
550 | iter 5 energy = -76.0107349333 delta = 2.29768e-03
|
---|
551 | 19108 integrals
|
---|
552 | iter 6 energy = -76.0107461220 delta = 5.11193e-04
|
---|
553 | 19108 integrals
|
---|
554 | iter 7 energy = -76.0107462842 delta = 5.25319e-05
|
---|
555 | 19108 integrals
|
---|
556 | iter 8 energy = -76.0107462976 delta = 1.68043e-05
|
---|
557 | 19108 integrals
|
---|
558 | iter 9 energy = -76.0107462983 delta = 4.02927e-06
|
---|
559 | 19108 integrals
|
---|
560 | iter 10 energy = -76.0107462984 delta = 1.15008e-06
|
---|
561 | 19108 integrals
|
---|
562 | iter 11 energy = -76.0107462984 delta = 1.44804e-07
|
---|
563 |
|
---|
564 | HOMO is 1 B1 = -0.498218
|
---|
565 | LUMO is 4 A1 = 0.213089
|
---|
566 |
|
---|
567 | total scf energy = -76.0107462984
|
---|
568 | Natural Population Analysis:
|
---|
569 | n atom charge ne(S) ne(P) ne(D)
|
---|
570 | 1 O -0.954701 3.748465 5.194988 0.011248
|
---|
571 | 2 H 0.477351 0.522649
|
---|
572 | 3 H 0.477351 0.522649
|
---|
573 |
|
---|
574 | SCF Parameters:
|
---|
575 | maxiter = 40
|
---|
576 | density_reset_frequency = 10
|
---|
577 | level_shift = 0.000000
|
---|
578 |
|
---|
579 | CLSCF Parameters:
|
---|
580 | charge = 0
|
---|
581 | ndocc = 5
|
---|
582 | docc = [ 3 0 1 1 ]
|
---|
583 |
|
---|
584 | CPU Wall
|
---|
585 | mpqc: 1.87 1.99
|
---|
586 | NAO: 0.21 0.22
|
---|
587 | vector: 0.18 0.20
|
---|
588 | density: 0.00 0.00
|
---|
589 | evals: 0.04 0.01
|
---|
590 | extrap: 0.02 0.01
|
---|
591 | fock: 0.04 0.09
|
---|
592 | accum: 0.00 0.00
|
---|
593 | ao_gmat: 0.03 0.03
|
---|
594 | start thread: 0.03 0.03
|
---|
595 | stop thread: 0.00 0.00
|
---|
596 | init pmax: 0.00 0.00
|
---|
597 | local data: 0.00 0.00
|
---|
598 | setup: 0.01 0.03
|
---|
599 | sum: 0.00 0.00
|
---|
600 | symm: 0.00 0.03
|
---|
601 | vector: 0.05 0.05
|
---|
602 | density: 0.00 0.00
|
---|
603 | evals: 0.00 0.00
|
---|
604 | extrap: 0.00 0.01
|
---|
605 | fock: 0.03 0.02
|
---|
606 | accum: 0.00 0.00
|
---|
607 | ao_gmat: 0.01 0.01
|
---|
608 | start thread: 0.01 0.00
|
---|
609 | stop thread: 0.00 0.00
|
---|
610 | init pmax: 0.00 0.00
|
---|
611 | local data: 0.00 0.00
|
---|
612 | setup: 0.01 0.01
|
---|
613 | sum: 0.00 0.00
|
---|
614 | symm: 0.01 0.01
|
---|
615 | calc: 0.12 0.13
|
---|
616 | vector: 0.11 0.13
|
---|
617 | density: 0.00 0.00
|
---|
618 | evals: 0.00 0.01
|
---|
619 | extrap: 0.00 0.01
|
---|
620 | fock: 0.09 0.09
|
---|
621 | accum: 0.00 0.00
|
---|
622 | ao_gmat: 0.04 0.03
|
---|
623 | start thread: 0.03 0.03
|
---|
624 | stop thread: 0.00 0.00
|
---|
625 | init pmax: 0.00 0.00
|
---|
626 | local data: 0.00 0.00
|
---|
627 | setup: 0.04 0.02
|
---|
628 | sum: 0.00 0.00
|
---|
629 | symm: 0.01 0.03
|
---|
630 | hessian: 1.35 1.42
|
---|
631 | compute gradient: 0.62 0.68
|
---|
632 | nuc rep: 0.00 0.00
|
---|
633 | one electron gradient: 0.06 0.07
|
---|
634 | overlap gradient: 0.05 0.03
|
---|
635 | two electron gradient: 0.51 0.57
|
---|
636 | contribution: 0.09 0.15
|
---|
637 | start thread: 0.09 0.11
|
---|
638 | stop thread: 0.00 0.03
|
---|
639 | setup: 0.42 0.42
|
---|
640 | vector: 0.69 0.71
|
---|
641 | density: 0.01 0.01
|
---|
642 | evals: 0.04 0.03
|
---|
643 | extrap: 0.03 0.05
|
---|
644 | fock: 0.42 0.40
|
---|
645 | accum: 0.00 0.00
|
---|
646 | ao_gmat: 0.16 0.17
|
---|
647 | start thread: 0.15 0.15
|
---|
648 | stop thread: 0.00 0.01
|
---|
649 | init pmax: 0.00 0.00
|
---|
650 | local data: 0.03 0.01
|
---|
651 | setup: 0.06 0.09
|
---|
652 | sum: 0.00 0.00
|
---|
653 | symm: 0.16 0.12
|
---|
654 | vector: 0.05 0.04
|
---|
655 | density: 0.00 0.00
|
---|
656 | evals: 0.00 0.00
|
---|
657 | extrap: 0.03 0.00
|
---|
658 | fock: 0.00 0.02
|
---|
659 | accum: 0.00 0.00
|
---|
660 | ao_gmat: 0.00 0.01
|
---|
661 | start thread: 0.00 0.00
|
---|
662 | stop thread: 0.00 0.00
|
---|
663 | init pmax: 0.00 0.00
|
---|
664 | local data: 0.00 0.00
|
---|
665 | setup: 0.00 0.00
|
---|
666 | sum: 0.00 0.00
|
---|
667 | symm: 0.00 0.01
|
---|
668 | input: 0.18 0.21
|
---|
669 | vector: 0.03 0.04
|
---|
670 | density: 0.00 0.00
|
---|
671 | evals: 0.01 0.00
|
---|
672 | extrap: 0.00 0.01
|
---|
673 | fock: 0.02 0.02
|
---|
674 | accum: 0.00 0.00
|
---|
675 | ao_gmat: 0.00 0.01
|
---|
676 | start thread: 0.00 0.00
|
---|
677 | stop thread: 0.00 0.00
|
---|
678 | init pmax: 0.00 0.00
|
---|
679 | local data: 0.00 0.00
|
---|
680 | setup: 0.01 0.01
|
---|
681 | sum: 0.00 0.00
|
---|
682 | symm: 0.00 0.01
|
---|
683 |
|
---|
684 | End Time: Sat Apr 6 14:00:28 2002
|
---|
685 |
|
---|