1 |
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2 | MPQC: Massively Parallel Quantum Chemistry
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3 | Version 2.1.0-alpha-gcc3
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4 |
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5 | Machine: i686-pc-linux-gnu
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6 | User: cljanss@aros.ca.sandia.gov
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7 | Start Time: Sat Apr 6 13:35:57 2002
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8 |
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9 | Using ProcMessageGrp for message passing (number of nodes = 1).
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10 | Using PthreadThreadGrp for threading (number of threads = 2).
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11 | Using ProcMemoryGrp for distributed shared memory.
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12 | Total number of processors = 2
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13 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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14 |
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15 | IntCoorGen: generated 3 coordinates.
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16 | Forming optimization coordinates:
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17 | SymmMolecularCoor::form_variable_coordinates()
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18 | expected 3 coordinates
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19 | found 2 variable coordinates
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20 | found 0 constant coordinates
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21 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/6-31gS.kv.
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22 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
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23 |
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24 | CLSCF::init: total charge = 0
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25 |
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26 | Starting from core Hamiltonian guess
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27 |
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28 | Using symmetric orthogonalization.
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29 | n(SO): 4 0 2 1
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30 | Maximum orthogonalization residual = 1.9104
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31 | Minimum orthogonalization residual = 0.344888
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32 | docc = [ 3 0 1 1 ]
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33 | nbasis = 7
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34 |
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35 | CLSCF::init: total charge = 0
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36 |
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37 | Projecting guess wavefunction into the present basis set
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38 |
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39 | SCF::compute: energy accuracy = 1.0000000e-06
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40 |
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41 | integral intermediate storage = 31876 bytes
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42 | integral cache = 31967676 bytes
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43 | nuclear repulsion energy = 9.1571164588
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44 |
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45 | 565 integrals
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46 | iter 1 energy = -74.6468200575 delta = 7.47315e-01
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47 | 565 integrals
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48 | iter 2 energy = -74.9403205745 delta = 2.28186e-01
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49 | 565 integrals
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50 | iter 3 energy = -74.9595588694 delta = 6.73664e-02
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51 | 565 integrals
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52 | iter 4 energy = -74.9606496999 delta = 1.99313e-02
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53 | 565 integrals
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54 | iter 5 energy = -74.9607021286 delta = 4.63824e-03
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55 | 565 integrals
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56 | iter 6 energy = -74.9607024815 delta = 3.51696e-04
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57 | 565 integrals
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58 | iter 7 energy = -74.9607024827 delta = 2.28520e-05
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59 |
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60 | HOMO is 1 B2 = -0.386942
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61 | LUMO is 4 A1 = 0.592900
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62 |
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63 | total scf energy = -74.9607024827
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64 |
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65 | Projecting the guess density.
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66 |
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67 | The number of electrons in the guess density = 10
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68 | Using symmetric orthogonalization.
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69 | n(SO): 10 1 5 3
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70 | Maximum orthogonalization residual = 4.65234
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71 | Minimum orthogonalization residual = 0.0224451
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72 | The number of electrons in the projected density = 9.95775
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73 |
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74 | docc = [ 3 0 1 1 ]
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75 | nbasis = 19
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76 |
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77 | Molecular formula H2O
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78 |
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79 | MPQC options:
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80 | matrixkit = <ReplSCMatrixKit>
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81 | filename = h2omp2_mp211631gsc2vopt
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82 | restart_file = h2omp2_mp211631gsc2vopt.ckpt
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83 | restart = no
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84 | checkpoint = no
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85 | savestate = no
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86 | do_energy = yes
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87 | do_gradient = no
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88 | optimize = yes
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89 | write_pdb = no
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90 | print_mole = yes
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91 | print_timings = yes
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92 |
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93 | Entered memgrp based MP2 routine
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94 | nproc = 1
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95 | Memory available per node: 32000000 Bytes
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96 | Static memory used per node: 9584 Bytes
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97 | Total memory used per node: 133376 Bytes
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98 | Memory required for one pass: 133376 Bytes
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99 | Minimum memory required: 56768 Bytes
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100 | Batch size: 4
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101 | npass rest nbasis nshell nfuncmax
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102 | 1 0 19 8 6
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103 | nocc nvir nfzc nfzv
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104 | 5 14 1 1
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105 |
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106 | SCF::compute: energy accuracy = 1.0000000e-08
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107 |
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108 | integral intermediate storage = 236328 bytes
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109 | integral cache = 31760632 bytes
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110 | nuclear repulsion energy = 9.1571164588
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111 |
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112 | 19108 integrals
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113 | iter 1 energy = -75.8312052141 delta = 2.13006e-01
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114 | 19108 integrals
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115 | iter 2 energy = -75.9878207300 delta = 5.78322e-02
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116 | 19108 integrals
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117 | iter 3 energy = -76.0050760043 delta = 1.50303e-02
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118 | 19108 integrals
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119 | iter 4 energy = -76.0095370808 delta = 6.94368e-03
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120 | 19108 integrals
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121 | iter 5 energy = -76.0098496950 delta = 2.33236e-03
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122 | 19108 integrals
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123 | iter 6 energy = -76.0098614083 delta = 5.22468e-04
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124 | 19108 integrals
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125 | iter 7 energy = -76.0098615983 delta = 5.73966e-05
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126 | 19108 integrals
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127 | iter 8 energy = -76.0098616150 delta = 1.91130e-05
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128 | 19108 integrals
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129 | iter 9 energy = -76.0098616160 delta = 4.72657e-06
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130 | 19108 integrals
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131 | iter 10 energy = -76.0098616161 delta = 1.30723e-06
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132 | 19108 integrals
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133 | iter 11 energy = -76.0098616161 delta = 1.40231e-07
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134 | 19108 integrals
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135 | iter 12 energy = -76.0098616161 delta = 2.86889e-08
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136 |
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137 | HOMO is 1 B2 = -0.495585
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138 | LUMO is 4 A1 = 0.210597
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139 |
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140 | total scf energy = -76.0098616161
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141 |
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142 | Memory used for integral intermediates: 823288 Bytes
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143 | Memory used for integral storage: 15531252 Bytes
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144 | Size of global distributed array: 57760 Bytes
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145 | Beginning pass 1
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146 | Begin loop over shells (erep, 1.+2. q.t.)
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147 | working on shell pair ( 0 0), 5.6% complete
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148 | working on shell pair ( 1 1), 11.1% complete
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149 | working on shell pair ( 2 1), 16.7% complete
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150 | working on shell pair ( 3 0), 22.2% complete
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151 | working on shell pair ( 3 2), 27.8% complete
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152 | working on shell pair ( 4 0), 33.3% complete
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153 | working on shell pair ( 4 2), 38.9% complete
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154 | working on shell pair ( 4 4), 44.4% complete
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155 | working on shell pair ( 5 1), 50.0% complete
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156 | working on shell pair ( 5 3), 55.6% complete
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157 | working on shell pair ( 5 5), 61.1% complete
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158 | working on shell pair ( 6 1), 66.7% complete
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159 | working on shell pair ( 6 3), 72.2% complete
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160 | working on shell pair ( 6 5), 77.8% complete
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161 | working on shell pair ( 7 0), 83.3% complete
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162 | working on shell pair ( 7 2), 88.9% complete
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163 | working on shell pair ( 7 4), 94.4% complete
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164 | working on shell pair ( 7 6), 100.0% complete
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165 | End of loop over shells
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166 | Begin third q.t.
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167 | End of third q.t.
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168 | Begin fourth q.t.
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169 | End of fourth q.t.
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170 | Begin third and fourth q.b.t.
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171 | working on shell pair ( 0 0), 5.6% complete
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172 | working on shell pair ( 1 1), 11.1% complete
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173 | working on shell pair ( 2 1), 16.7% complete
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174 | working on shell pair ( 3 0), 22.2% complete
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175 | working on shell pair ( 3 2), 27.8% complete
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176 | working on shell pair ( 4 0), 33.3% complete
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177 | working on shell pair ( 4 2), 38.9% complete
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178 | working on shell pair ( 4 4), 44.4% complete
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179 | working on shell pair ( 5 1), 50.0% complete
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180 | working on shell pair ( 5 3), 55.6% complete
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181 | working on shell pair ( 5 5), 61.1% complete
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182 | working on shell pair ( 6 1), 66.7% complete
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183 | working on shell pair ( 6 3), 72.2% complete
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184 | working on shell pair ( 6 5), 77.8% complete
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185 | working on shell pair ( 7 0), 83.3% complete
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186 | working on shell pair ( 7 2), 88.9% complete
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187 | working on shell pair ( 7 4), 94.4% complete
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188 | working on shell pair ( 7 6), 100.0% complete
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189 | End of third and fourth q.b.t.
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190 | Done with pass 1
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191 |
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192 | Largest first order coefficients (unique):
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193 | 1 -0.04780278 1 B2 1 B2 -> 2 B2 2 B2 (+-+-)
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194 | 2 -0.03776445 3 A1 3 A1 -> 6 A1 6 A1 (+-+-)
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195 | 3 -0.03250484 1 B1 1 B1 -> 2 B1 2 B1 (+-+-)
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196 | 4 -0.03197563 1 B2 3 A1 -> 2 B2 6 A1 (+-+-)
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197 | 5 -0.02778214 1 B2 3 A1 -> 2 B2 6 A1 (++++)
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198 | 6 -0.02666217 1 B2 1 B1 -> 2 B2 4 B1 (+-+-)
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199 | 7 -0.02637247 1 B1 1 B1 -> 4 B1 4 B1 (+-+-)
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200 | 8 -0.02546470 1 B2 1 B1 -> 2 B2 2 B1 (+-+-)
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201 | 9 -0.02386922 3 A1 1 B1 -> 6 A1 4 B1 (+-+-)
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202 | 10 -0.02362178 1 B1 1 B1 -> 3 B1 3 B1 (+-+-)
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203 |
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204 | RHF energy [au]: -76.009861616070
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205 | MP2 correlation energy [au]: -0.176527601495
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206 | MP2 energy [au]: -76.186389217565
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207 |
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208 | D1(MP2) = 0.00734281
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209 | S2 matrix 1-norm = 0.00805452
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210 | S2 matrix inf-norm = 0.01472069
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211 | S2 diagnostic = 0.00448692
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212 |
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213 | Largest S2 values (unique determinants):
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214 | 1 0.00556708 1 B2 -> 2 B2
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215 | 2 -0.00501763 1 B1 -> 4 B1
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216 | 3 0.00491522 3 A1 -> 4 A1
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217 | 4 0.00438499 1 B1 -> 2 B1
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218 | 5 0.00369516 2 A1 -> 6 A1
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219 | 6 -0.00313930 2 A1 -> 4 A1
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220 | 7 0.00308629 3 A1 -> 5 A1
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221 | 8 -0.00272975 1 B1 -> 5 B1
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222 | 9 0.00239871 3 A1 -> 7 A1
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223 | 10 0.00230065 2 A1 -> 5 A1
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224 |
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225 | D2(MP1) = 0.10513274
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226 |
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227 | CPHF: iter = 1 rms(P) = 0.0056600645 eps = 0.0000000100
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228 | CPHF: iter = 2 rms(P) = 0.0017366027 eps = 0.0000000100
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229 | CPHF: iter = 3 rms(P) = 0.0001804665 eps = 0.0000000100
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230 | CPHF: iter = 4 rms(P) = 0.0000214688 eps = 0.0000000100
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231 | CPHF: iter = 5 rms(P) = 0.0000048149 eps = 0.0000000100
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232 | CPHF: iter = 6 rms(P) = 0.0000004920 eps = 0.0000000100
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233 | CPHF: iter = 7 rms(P) = 0.0000000286 eps = 0.0000000100
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234 | CPHF: iter = 8 rms(P) = 0.0000000018 eps = 0.0000000100
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235 |
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236 | Total MP2 gradient [au]:
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237 | 1 O 0.0000000000 -0.0000000000 -0.0189517814
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238 | 2 H 0.0006141493 -0.0000000000 0.0094758907
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239 | 3 H -0.0006141493 0.0000000000 0.0094758907
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240 |
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241 | Max Gradient : 0.0189517814 0.0001000000 no
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242 | Max Displacement : 0.0320605053 0.0001000000 no
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243 | Gradient*Displace: 0.0009334167 0.0001000000 no
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244 |
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245 | taking step of size 0.057691
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246 |
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247 | MBPT2: changing atomic coordinates:
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248 | Molecular formula: H2O
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249 | molecule<Molecule>: (
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250 | symmetry = c2v
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251 | unit = "angstrom"
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252 | { n atoms geometry }={
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253 | 1 O [ 0.0000000000 -0.0000000000 0.3863386340]
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254 | 2 H [ 0.7744930176 0.0000000000 -0.1931693170]
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255 | 3 H [ -0.7744930176 -0.0000000000 -0.1931693170]
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256 | }
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257 | )
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258 | Atomic Masses:
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259 | 15.99491 1.00783 1.00783
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260 | Using symmetric orthogonalization.
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261 | n(SO): 10 1 5 3
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262 | Maximum orthogonalization residual = 4.64604
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263 | Minimum orthogonalization residual = 0.0226762
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264 |
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265 | Entered memgrp based MP2 routine
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266 | nproc = 1
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267 | Memory available per node: 32000000 Bytes
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268 | Static memory used per node: 9584 Bytes
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269 | Total memory used per node: 133376 Bytes
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270 | Memory required for one pass: 133376 Bytes
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271 | Minimum memory required: 56768 Bytes
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272 | Batch size: 4
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273 | npass rest nbasis nshell nfuncmax
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274 | 1 0 19 8 6
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275 | nocc nvir nfzc nfzv
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276 | 5 14 1 1
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277 |
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278 | SCF::compute: energy accuracy = 1.0000000e-08
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279 |
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280 | integral intermediate storage = 236328 bytes
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281 | integral cache = 31760632 bytes
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282 | nuclear repulsion energy = 9.0946910677
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283 |
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284 | Using symmetric orthogonalization.
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285 | n(SO): 10 1 5 3
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286 | Maximum orthogonalization residual = 4.64604
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287 | Minimum orthogonalization residual = 0.0226762
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288 | 19108 integrals
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289 | iter 1 energy = -76.0092805260 delta = 2.09316e-01
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290 | 19108 integrals
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291 | iter 2 energy = -76.0098191323 delta = 3.72023e-03
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292 | 19108 integrals
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293 | iter 3 energy = -76.0098568020 delta = 9.00768e-04
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294 | 19108 integrals
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295 | iter 4 energy = -76.0098639239 delta = 3.06535e-04
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296 | 19108 integrals
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297 | iter 5 energy = -76.0098653908 delta = 1.58914e-04
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298 | 19108 integrals
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299 | iter 6 energy = -76.0098655654 delta = 7.45080e-05
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300 | 19108 integrals
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301 | iter 7 energy = -76.0098655665 delta = 5.43309e-06
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302 | 19108 integrals
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303 | iter 8 energy = -76.0098655665 delta = 9.46028e-07
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304 | 19108 integrals
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305 | iter 9 energy = -76.0098655665 delta = 1.29172e-07
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306 | 19108 integrals
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307 | iter 10 energy = -76.0098655665 delta = 4.50437e-08
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308 | 19108 integrals
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309 | iter 11 energy = -76.0098655665 delta = 1.01424e-08
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310 |
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311 | HOMO is 1 B2 = -0.496426
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312 | LUMO is 4 A1 = 0.208755
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313 |
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314 | total scf energy = -76.0098655665
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315 |
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316 | Memory used for integral intermediates: 823288 Bytes
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317 | Memory used for integral storage: 15531252 Bytes
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318 | Size of global distributed array: 57760 Bytes
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319 | Beginning pass 1
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320 | Begin loop over shells (erep, 1.+2. q.t.)
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321 | working on shell pair ( 0 0), 5.6% complete
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322 | working on shell pair ( 1 1), 11.1% complete
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323 | working on shell pair ( 2 1), 16.7% complete
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324 | working on shell pair ( 3 0), 22.2% complete
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325 | working on shell pair ( 3 2), 27.8% complete
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326 | working on shell pair ( 4 0), 33.3% complete
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327 | working on shell pair ( 4 2), 38.9% complete
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328 | working on shell pair ( 4 4), 44.4% complete
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329 | working on shell pair ( 5 1), 50.0% complete
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330 | working on shell pair ( 5 3), 55.6% complete
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331 | working on shell pair ( 5 5), 61.1% complete
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332 | working on shell pair ( 6 1), 66.7% complete
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333 | working on shell pair ( 6 3), 72.2% complete
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334 | working on shell pair ( 6 5), 77.8% complete
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335 | working on shell pair ( 7 0), 83.3% complete
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336 | working on shell pair ( 7 2), 88.9% complete
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337 | working on shell pair ( 7 4), 94.4% complete
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338 | working on shell pair ( 7 6), 100.0% complete
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339 | End of loop over shells
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340 | Begin third q.t.
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341 | End of third q.t.
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342 | Begin fourth q.t.
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343 | End of fourth q.t.
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344 | Begin third and fourth q.b.t.
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345 | working on shell pair ( 0 0), 5.6% complete
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346 | working on shell pair ( 1 1), 11.1% complete
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347 | working on shell pair ( 2 1), 16.7% complete
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348 | working on shell pair ( 3 0), 22.2% complete
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349 | working on shell pair ( 3 2), 27.8% complete
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350 | working on shell pair ( 4 0), 33.3% complete
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351 | working on shell pair ( 4 2), 38.9% complete
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352 | working on shell pair ( 4 4), 44.4% complete
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353 | working on shell pair ( 5 1), 50.0% complete
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354 | working on shell pair ( 5 3), 55.6% complete
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355 | working on shell pair ( 5 5), 61.1% complete
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356 | working on shell pair ( 6 1), 66.7% complete
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357 | working on shell pair ( 6 3), 72.2% complete
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358 | working on shell pair ( 6 5), 77.8% complete
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359 | working on shell pair ( 7 0), 83.3% complete
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360 | working on shell pair ( 7 2), 88.9% complete
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361 | working on shell pair ( 7 4), 94.4% complete
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362 | working on shell pair ( 7 6), 100.0% complete
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363 | End of third and fourth q.b.t.
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364 | Done with pass 1
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365 |
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366 | Largest first order coefficients (unique):
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367 | 1 -0.04778768 1 B2 1 B2 -> 2 B2 2 B2 (+-+-)
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368 | 2 -0.03561566 3 A1 3 A1 -> 6 A1 6 A1 (+-+-)
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369 | 3 -0.03380817 1 B1 1 B1 -> 2 B1 2 B1 (+-+-)
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370 | 4 -0.03071574 1 B2 3 A1 -> 2 B2 6 A1 (+-+-)
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371 | 5 -0.02701290 1 B2 3 A1 -> 2 B2 6 A1 (++++)
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372 | 6 -0.02672416 1 B2 1 B1 -> 2 B2 4 B1 (+-+-)
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373 | 7 -0.02642839 1 B1 1 B1 -> 4 B1 4 B1 (+-+-)
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374 | 8 -0.02579472 1 B2 1 B1 -> 2 B2 2 B1 (+-+-)
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375 | 9 -0.02390209 1 B1 1 B1 -> 3 B1 3 B1 (+-+-)
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376 | 10 -0.02340097 3 A1 1 B1 -> 6 A1 4 B1 (+-+-)
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377 |
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378 | RHF energy [au]: -76.009865566526
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379 | MP2 correlation energy [au]: -0.177152130949
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380 | MP2 energy [au]: -76.187017697475
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381 |
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382 | D1(MP2) = 0.00750853
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383 | S2 matrix 1-norm = 0.00801979
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384 | S2 matrix inf-norm = 0.01477835
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385 | S2 diagnostic = 0.00456693
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386 |
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387 | Largest S2 values (unique determinants):
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388 | 1 0.00563578 1 B2 -> 2 B2
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389 | 2 -0.00522362 1 B1 -> 4 B1
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390 | 3 0.00515368 3 A1 -> 4 A1
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391 | 4 0.00437326 1 B1 -> 2 B1
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392 | 5 -0.00353203 2 A1 -> 6 A1
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393 | 6 0.00325458 3 A1 -> 5 A1
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394 | 7 0.00286611 2 A1 -> 4 A1
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395 | 8 -0.00282155 1 B1 -> 5 B1
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396 | 9 -0.00273822 2 A1 -> 5 A1
|
---|
397 | 10 0.00249651 3 A1 -> 7 A1
|
---|
398 |
|
---|
399 | D2(MP1) = 0.10617922
|
---|
400 |
|
---|
401 | CPHF: iter = 1 rms(P) = 0.0056353568 eps = 0.0000000100
|
---|
402 | CPHF: iter = 2 rms(P) = 0.0018009449 eps = 0.0000000100
|
---|
403 | CPHF: iter = 3 rms(P) = 0.0001911082 eps = 0.0000000100
|
---|
404 | CPHF: iter = 4 rms(P) = 0.0000238853 eps = 0.0000000100
|
---|
405 | CPHF: iter = 5 rms(P) = 0.0000051721 eps = 0.0000000100
|
---|
406 | CPHF: iter = 6 rms(P) = 0.0000005427 eps = 0.0000000100
|
---|
407 | CPHF: iter = 7 rms(P) = 0.0000000320 eps = 0.0000000100
|
---|
408 | CPHF: iter = 8 rms(P) = 0.0000000021 eps = 0.0000000100
|
---|
409 |
|
---|
410 | Total MP2 gradient [au]:
|
---|
411 | 1 O -0.0000000000 -0.0000000000 -0.0045746673
|
---|
412 | 2 H 0.0026923402 -0.0000000000 0.0022873337
|
---|
413 | 3 H -0.0026923402 0.0000000000 0.0022873337
|
---|
414 |
|
---|
415 | Max Gradient : 0.0045746673 0.0001000000 no
|
---|
416 | Max Displacement : 0.0241981982 0.0001000000 no
|
---|
417 | Gradient*Displace: 0.0002605155 0.0001000000 no
|
---|
418 |
|
---|
419 | taking step of size 0.040936
|
---|
420 |
|
---|
421 | MBPT2: changing atomic coordinates:
|
---|
422 | Molecular formula: H2O
|
---|
423 | molecule<Molecule>: (
|
---|
424 | symmetry = c2v
|
---|
425 | unit = "angstrom"
|
---|
426 | { n atoms geometry }={
|
---|
427 | 1 O [ 0.0000000000 -0.0000000000 0.3963805003]
|
---|
428 | 2 H [ 0.7616878816 0.0000000000 -0.1981902501]
|
---|
429 | 3 H [ -0.7616878816 -0.0000000000 -0.1981902501]
|
---|
430 | }
|
---|
431 | )
|
---|
432 | Atomic Masses:
|
---|
433 | 15.99491 1.00783 1.00783
|
---|
434 | Using symmetric orthogonalization.
|
---|
435 | n(SO): 10 1 5 3
|
---|
436 | Maximum orthogonalization residual = 4.65673
|
---|
437 | Minimum orthogonalization residual = 0.0226174
|
---|
438 |
|
---|
439 | Entered memgrp based MP2 routine
|
---|
440 | nproc = 1
|
---|
441 | Memory available per node: 32000000 Bytes
|
---|
442 | Static memory used per node: 9584 Bytes
|
---|
443 | Total memory used per node: 133376 Bytes
|
---|
444 | Memory required for one pass: 133376 Bytes
|
---|
445 | Minimum memory required: 56768 Bytes
|
---|
446 | Batch size: 4
|
---|
447 | npass rest nbasis nshell nfuncmax
|
---|
448 | 1 0 19 8 6
|
---|
449 | nocc nvir nfzc nfzv
|
---|
450 | 5 14 1 1
|
---|
451 |
|
---|
452 | SCF::compute: energy accuracy = 1.0000000e-08
|
---|
453 |
|
---|
454 | integral intermediate storage = 236328 bytes
|
---|
455 | integral cache = 31760632 bytes
|
---|
456 | nuclear repulsion energy = 9.1097389984
|
---|
457 |
|
---|
458 | Using symmetric orthogonalization.
|
---|
459 | n(SO): 10 1 5 3
|
---|
460 | Maximum orthogonalization residual = 4.65673
|
---|
461 | Minimum orthogonalization residual = 0.0226174
|
---|
462 | 19108 integrals
|
---|
463 | iter 1 energy = -76.0097429013 delta = 2.09666e-01
|
---|
464 | 19108 integrals
|
---|
465 | iter 2 energy = -76.0099785437 delta = 2.04468e-03
|
---|
466 | 19108 integrals
|
---|
467 | iter 3 energy = -76.0099901900 delta = 4.85833e-04
|
---|
468 | 19108 integrals
|
---|
469 | iter 4 energy = -76.0099912082 delta = 1.24672e-04
|
---|
470 | 19108 integrals
|
---|
471 | iter 5 energy = -76.0099914510 delta = 5.28765e-05
|
---|
472 | 19108 integrals
|
---|
473 | iter 6 energy = -76.0099915163 delta = 4.63142e-05
|
---|
474 | 19108 integrals
|
---|
475 | iter 7 energy = -76.0099915165 delta = 2.34062e-06
|
---|
476 | 19108 integrals
|
---|
477 | iter 8 energy = -76.0099915165 delta = 2.68270e-07
|
---|
478 | 19108 integrals
|
---|
479 | iter 9 energy = -76.0099915165 delta = 2.65793e-08
|
---|
480 |
|
---|
481 | HOMO is 1 B2 = -0.497487
|
---|
482 | LUMO is 4 A1 = 0.208717
|
---|
483 |
|
---|
484 | total scf energy = -76.0099915165
|
---|
485 |
|
---|
486 | Memory used for integral intermediates: 823288 Bytes
|
---|
487 | Memory used for integral storage: 15531252 Bytes
|
---|
488 | Size of global distributed array: 57760 Bytes
|
---|
489 | Beginning pass 1
|
---|
490 | Begin loop over shells (erep, 1.+2. q.t.)
|
---|
491 | working on shell pair ( 0 0), 5.6% complete
|
---|
492 | working on shell pair ( 1 1), 11.1% complete
|
---|
493 | working on shell pair ( 2 1), 16.7% complete
|
---|
494 | working on shell pair ( 3 0), 22.2% complete
|
---|
495 | working on shell pair ( 3 2), 27.8% complete
|
---|
496 | working on shell pair ( 4 0), 33.3% complete
|
---|
497 | working on shell pair ( 4 2), 38.9% complete
|
---|
498 | working on shell pair ( 4 4), 44.4% complete
|
---|
499 | working on shell pair ( 5 1), 50.0% complete
|
---|
500 | working on shell pair ( 5 3), 55.6% complete
|
---|
501 | working on shell pair ( 5 5), 61.1% complete
|
---|
502 | working on shell pair ( 6 1), 66.7% complete
|
---|
503 | working on shell pair ( 6 3), 72.2% complete
|
---|
504 | working on shell pair ( 6 5), 77.8% complete
|
---|
505 | working on shell pair ( 7 0), 83.3% complete
|
---|
506 | working on shell pair ( 7 2), 88.9% complete
|
---|
507 | working on shell pair ( 7 4), 94.4% complete
|
---|
508 | working on shell pair ( 7 6), 100.0% complete
|
---|
509 | End of loop over shells
|
---|
510 | Begin third q.t.
|
---|
511 | End of third q.t.
|
---|
512 | Begin fourth q.t.
|
---|
513 | End of fourth q.t.
|
---|
514 | Begin third and fourth q.b.t.
|
---|
515 | working on shell pair ( 0 0), 5.6% complete
|
---|
516 | working on shell pair ( 1 1), 11.1% complete
|
---|
517 | working on shell pair ( 2 1), 16.7% complete
|
---|
518 | working on shell pair ( 3 0), 22.2% complete
|
---|
519 | working on shell pair ( 3 2), 27.8% complete
|
---|
520 | working on shell pair ( 4 0), 33.3% complete
|
---|
521 | working on shell pair ( 4 2), 38.9% complete
|
---|
522 | working on shell pair ( 4 4), 44.4% complete
|
---|
523 | working on shell pair ( 5 1), 50.0% complete
|
---|
524 | working on shell pair ( 5 3), 55.6% complete
|
---|
525 | working on shell pair ( 5 5), 61.1% complete
|
---|
526 | working on shell pair ( 6 1), 66.7% complete
|
---|
527 | working on shell pair ( 6 3), 72.2% complete
|
---|
528 | working on shell pair ( 6 5), 77.8% complete
|
---|
529 | working on shell pair ( 7 0), 83.3% complete
|
---|
530 | working on shell pair ( 7 2), 88.9% complete
|
---|
531 | working on shell pair ( 7 4), 94.4% complete
|
---|
532 | working on shell pair ( 7 6), 100.0% complete
|
---|
533 | End of third and fourth q.b.t.
|
---|
534 | Done with pass 1
|
---|
535 |
|
---|
536 | Largest first order coefficients (unique):
|
---|
537 | 1 -0.04776779 1 B2 1 B2 -> 2 B2 2 B2 (+-+-)
|
---|
538 | 2 -0.03420530 1 B1 1 B1 -> 2 B1 2 B1 (+-+-)
|
---|
539 | 3 -0.03049471 3 A1 3 A1 -> 6 A1 6 A1 (+-+-)
|
---|
540 | 4 -0.02758560 1 B2 3 A1 -> 2 B2 6 A1 (+-+-)
|
---|
541 | 5 0.02680779 1 B2 1 B1 -> 2 B2 4 B1 (+-+-)
|
---|
542 | 6 -0.02661040 1 B1 1 B1 -> 4 B1 4 B1 (+-+-)
|
---|
543 | 7 0.02586573 1 B2 1 B1 -> 2 B2 2 B1 (+-+-)
|
---|
544 | 8 -0.02485096 1 B2 3 A1 -> 2 B2 6 A1 (++++)
|
---|
545 | 9 -0.02398527 1 B1 1 B1 -> 3 B1 3 B1 (+-+-)
|
---|
546 | 10 0.02327574 1 B2 1 B1 -> 2 B2 2 B1 (++++)
|
---|
547 |
|
---|
548 | RHF energy [au]: -76.009991516536
|
---|
549 | MP2 correlation energy [au]: -0.177131339962
|
---|
550 | MP2 energy [au]: -76.187122856498
|
---|
551 |
|
---|
552 | D1(MP2) = 0.00756070
|
---|
553 | S2 matrix 1-norm = 0.00792410
|
---|
554 | S2 matrix inf-norm = 0.01415113
|
---|
555 | S2 diagnostic = 0.00458483
|
---|
556 |
|
---|
557 | Largest S2 values (unique determinants):
|
---|
558 | 1 0.00566121 1 B2 -> 2 B2
|
---|
559 | 2 0.00525592 1 B1 -> 4 B1
|
---|
560 | 3 -0.00520251 3 A1 -> 4 A1
|
---|
561 | 4 -0.00442827 1 B1 -> 2 B1
|
---|
562 | 5 0.00342472 2 A1 -> 5 A1
|
---|
563 | 6 0.00341157 3 A1 -> 5 A1
|
---|
564 | 7 0.00292581 2 A1 -> 6 A1
|
---|
565 | 8 -0.00282899 1 B1 -> 5 B1
|
---|
566 | 9 0.00272159 2 A1 -> 4 A1
|
---|
567 | 10 0.00247394 3 A1 -> 7 A1
|
---|
568 |
|
---|
569 | D2(MP1) = 0.10634835
|
---|
570 |
|
---|
571 | CPHF: iter = 1 rms(P) = 0.0056183644 eps = 0.0000000100
|
---|
572 | CPHF: iter = 2 rms(P) = 0.0018042416 eps = 0.0000000100
|
---|
573 | CPHF: iter = 3 rms(P) = 0.0001943821 eps = 0.0000000100
|
---|
574 | CPHF: iter = 4 rms(P) = 0.0000246670 eps = 0.0000000100
|
---|
575 | CPHF: iter = 5 rms(P) = 0.0000053188 eps = 0.0000000100
|
---|
576 | CPHF: iter = 6 rms(P) = 0.0000005591 eps = 0.0000000100
|
---|
577 | CPHF: iter = 7 rms(P) = 0.0000000328 eps = 0.0000000100
|
---|
578 | CPHF: iter = 8 rms(P) = 0.0000000021 eps = 0.0000000100
|
---|
579 |
|
---|
580 | Total MP2 gradient [au]:
|
---|
581 | 1 O -0.0000000000 -0.0000000000 -0.0009193050
|
---|
582 | 2 H -0.0015939718 -0.0000000000 0.0004596525
|
---|
583 | 3 H 0.0015939718 0.0000000000 0.0004596525
|
---|
584 |
|
---|
585 | Max Gradient : 0.0015939718 0.0001000000 no
|
---|
586 | Max Displacement : 0.0052729567 0.0001000000 no
|
---|
587 | Gradient*Displace: 0.0000151463 0.0001000000 yes
|
---|
588 |
|
---|
589 | taking step of size 0.006684
|
---|
590 |
|
---|
591 | MBPT2: changing atomic coordinates:
|
---|
592 | Molecular formula: H2O
|
---|
593 | molecule<Molecule>: (
|
---|
594 | symmetry = c2v
|
---|
595 | unit = "angstrom"
|
---|
596 | { n atoms geometry }={
|
---|
597 | 1 O [ -0.0000000000 0.0000000000 0.3957420907]
|
---|
598 | 2 H [ 0.7644782103 0.0000000000 -0.1978710453]
|
---|
599 | 3 H [ -0.7644782103 -0.0000000000 -0.1978710453]
|
---|
600 | }
|
---|
601 | )
|
---|
602 | Atomic Masses:
|
---|
603 | 15.99491 1.00783 1.00783
|
---|
604 | Using symmetric orthogonalization.
|
---|
605 | n(SO): 10 1 5 3
|
---|
606 | Maximum orthogonalization residual = 4.65195
|
---|
607 | Minimum orthogonalization residual = 0.0226795
|
---|
608 |
|
---|
609 | Entered memgrp based MP2 routine
|
---|
610 | nproc = 1
|
---|
611 | Memory available per node: 32000000 Bytes
|
---|
612 | Static memory used per node: 9584 Bytes
|
---|
613 | Total memory used per node: 133376 Bytes
|
---|
614 | Memory required for one pass: 133376 Bytes
|
---|
615 | Minimum memory required: 56768 Bytes
|
---|
616 | Batch size: 4
|
---|
617 | npass rest nbasis nshell nfuncmax
|
---|
618 | 1 0 19 8 6
|
---|
619 | nocc nvir nfzc nfzv
|
---|
620 | 5 14 1 1
|
---|
621 |
|
---|
622 | SCF::compute: energy accuracy = 1.0000000e-08
|
---|
623 |
|
---|
624 | integral intermediate storage = 236328 bytes
|
---|
625 | integral cache = 31760632 bytes
|
---|
626 | nuclear repulsion energy = 9.0938643105
|
---|
627 |
|
---|
628 | Using symmetric orthogonalization.
|
---|
629 | n(SO): 10 1 5 3
|
---|
630 | Maximum orthogonalization residual = 4.65195
|
---|
631 | Minimum orthogonalization residual = 0.0226795
|
---|
632 | 19108 integrals
|
---|
633 | iter 1 energy = -76.0098688803 delta = 2.09978e-01
|
---|
634 | 19108 integrals
|
---|
635 | iter 2 energy = -76.0098776050 delta = 3.30402e-04
|
---|
636 | 19108 integrals
|
---|
637 | iter 3 energy = -76.0098779285 delta = 7.57428e-05
|
---|
638 | 19108 integrals
|
---|
639 | iter 4 energy = -76.0098779860 delta = 2.49969e-05
|
---|
640 | 19108 integrals
|
---|
641 | iter 5 energy = -76.0098779916 delta = 8.06046e-06
|
---|
642 | 19108 integrals
|
---|
643 | iter 6 energy = -76.0098779922 delta = 3.32620e-06
|
---|
644 | 19108 integrals
|
---|
645 | iter 7 energy = -76.0098779922 delta = 5.82305e-07
|
---|
646 | 19108 integrals
|
---|
647 | iter 8 energy = -76.0098779922 delta = 1.26146e-07
|
---|
648 | 19108 integrals
|
---|
649 | iter 9 energy = -76.0098779922 delta = 4.10155e-08
|
---|
650 |
|
---|
651 | HOMO is 1 B2 = -0.497258
|
---|
652 | LUMO is 4 A1 = 0.208404
|
---|
653 |
|
---|
654 | total scf energy = -76.0098779922
|
---|
655 |
|
---|
656 | Memory used for integral intermediates: 823288 Bytes
|
---|
657 | Memory used for integral storage: 15531252 Bytes
|
---|
658 | Size of global distributed array: 57760 Bytes
|
---|
659 | Beginning pass 1
|
---|
660 | Begin loop over shells (erep, 1.+2. q.t.)
|
---|
661 | working on shell pair ( 0 0), 5.6% complete
|
---|
662 | working on shell pair ( 1 1), 11.1% complete
|
---|
663 | working on shell pair ( 2 1), 16.7% complete
|
---|
664 | working on shell pair ( 3 0), 22.2% complete
|
---|
665 | working on shell pair ( 3 2), 27.8% complete
|
---|
666 | working on shell pair ( 4 0), 33.3% complete
|
---|
667 | working on shell pair ( 4 2), 38.9% complete
|
---|
668 | working on shell pair ( 4 4), 44.4% complete
|
---|
669 | working on shell pair ( 5 1), 50.0% complete
|
---|
670 | working on shell pair ( 5 3), 55.6% complete
|
---|
671 | working on shell pair ( 5 5), 61.1% complete
|
---|
672 | working on shell pair ( 6 1), 66.7% complete
|
---|
673 | working on shell pair ( 6 3), 72.2% complete
|
---|
674 | working on shell pair ( 6 5), 77.8% complete
|
---|
675 | working on shell pair ( 7 0), 83.3% complete
|
---|
676 | working on shell pair ( 7 2), 88.9% complete
|
---|
677 | working on shell pair ( 7 4), 94.4% complete
|
---|
678 | working on shell pair ( 7 6), 100.0% complete
|
---|
679 | End of loop over shells
|
---|
680 | Begin third q.t.
|
---|
681 | End of third q.t.
|
---|
682 | Begin fourth q.t.
|
---|
683 | End of fourth q.t.
|
---|
684 | Begin third and fourth q.b.t.
|
---|
685 | working on shell pair ( 0 0), 5.6% complete
|
---|
686 | working on shell pair ( 1 1), 11.1% complete
|
---|
687 | working on shell pair ( 2 1), 16.7% complete
|
---|
688 | working on shell pair ( 3 0), 22.2% complete
|
---|
689 | working on shell pair ( 3 2), 27.8% complete
|
---|
690 | working on shell pair ( 4 0), 33.3% complete
|
---|
691 | working on shell pair ( 4 2), 38.9% complete
|
---|
692 | working on shell pair ( 4 4), 44.4% complete
|
---|
693 | working on shell pair ( 5 1), 50.0% complete
|
---|
694 | working on shell pair ( 5 3), 55.6% complete
|
---|
695 | working on shell pair ( 5 5), 61.1% complete
|
---|
696 | working on shell pair ( 6 1), 66.7% complete
|
---|
697 | working on shell pair ( 6 3), 72.2% complete
|
---|
698 | working on shell pair ( 6 5), 77.8% complete
|
---|
699 | working on shell pair ( 7 0), 83.3% complete
|
---|
700 | working on shell pair ( 7 2), 88.9% complete
|
---|
701 | working on shell pair ( 7 4), 94.4% complete
|
---|
702 | working on shell pair ( 7 6), 100.0% complete
|
---|
703 | End of third and fourth q.b.t.
|
---|
704 | Done with pass 1
|
---|
705 |
|
---|
706 | Largest first order coefficients (unique):
|
---|
707 | 1 -0.04777222 1 B2 1 B2 -> 2 B2 2 B2 (+-+-)
|
---|
708 | 2 -0.03429517 1 B1 1 B1 -> 2 B1 2 B1 (+-+-)
|
---|
709 | 3 -0.03191042 3 A1 3 A1 -> 6 A1 6 A1 (+-+-)
|
---|
710 | 4 -0.02846692 1 B2 3 A1 -> 2 B2 6 A1 (+-+-)
|
---|
711 | 5 0.02679043 1 B2 1 B1 -> 2 B2 4 B1 (+-+-)
|
---|
712 | 6 -0.02655801 1 B1 1 B1 -> 4 B1 4 B1 (+-+-)
|
---|
713 | 7 0.02589689 1 B2 1 B1 -> 2 B2 2 B1 (+-+-)
|
---|
714 | 8 -0.02548555 1 B2 3 A1 -> 2 B2 6 A1 (++++)
|
---|
715 | 9 -0.02399880 1 B1 1 B1 -> 3 B1 3 B1 (+-+-)
|
---|
716 | 10 0.02330689 1 B2 1 B1 -> 2 B2 2 B1 (++++)
|
---|
717 |
|
---|
718 | RHF energy [au]: -76.009877992200
|
---|
719 | MP2 correlation energy [au]: -0.177251727935
|
---|
720 | MP2 energy [au]: -76.187129720135
|
---|
721 |
|
---|
722 | D1(MP2) = 0.00757238
|
---|
723 | S2 matrix 1-norm = 0.00794923
|
---|
724 | S2 matrix inf-norm = 0.01437001
|
---|
725 | S2 diagnostic = 0.00459309
|
---|
726 |
|
---|
727 | Largest S2 values (unique determinants):
|
---|
728 | 1 0.00566408 1 B2 -> 2 B2
|
---|
729 | 2 0.00527952 1 B1 -> 4 B1
|
---|
730 | 3 -0.00522456 3 A1 -> 4 A1
|
---|
731 | 4 -0.00441035 1 B1 -> 2 B1
|
---|
732 | 5 0.00338537 3 A1 -> 5 A1
|
---|
733 | 6 0.00327400 2 A1 -> 5 A1
|
---|
734 | 7 0.00310431 2 A1 -> 6 A1
|
---|
735 | 8 -0.00284245 1 B1 -> 5 B1
|
---|
736 | 9 0.00272467 2 A1 -> 4 A1
|
---|
737 | 10 0.00249988 3 A1 -> 7 A1
|
---|
738 |
|
---|
739 | D2(MP1) = 0.10647289
|
---|
740 |
|
---|
741 | CPHF: iter = 1 rms(P) = 0.0056205659 eps = 0.0000000100
|
---|
742 | CPHF: iter = 2 rms(P) = 0.0018134123 eps = 0.0000000100
|
---|
743 | CPHF: iter = 3 rms(P) = 0.0001950729 eps = 0.0000000100
|
---|
744 | CPHF: iter = 4 rms(P) = 0.0000247767 eps = 0.0000000100
|
---|
745 | CPHF: iter = 5 rms(P) = 0.0000053235 eps = 0.0000000100
|
---|
746 | CPHF: iter = 6 rms(P) = 0.0000005629 eps = 0.0000000100
|
---|
747 | CPHF: iter = 7 rms(P) = 0.0000000331 eps = 0.0000000100
|
---|
748 | CPHF: iter = 8 rms(P) = 0.0000000021 eps = 0.0000000100
|
---|
749 |
|
---|
750 | Total MP2 gradient [au]:
|
---|
751 | 1 O 0.0000000000 -0.0000000000 0.0002854723
|
---|
752 | 2 H 0.0001820786 -0.0000000000 -0.0001427361
|
---|
753 | 3 H -0.0001820786 0.0000000000 -0.0001427361
|
---|
754 |
|
---|
755 | Max Gradient : 0.0002854723 0.0001000000 no
|
---|
756 | Max Displacement : 0.0003094279 0.0001000000 no
|
---|
757 | Gradient*Displace: 0.0000002191 0.0001000000 yes
|
---|
758 |
|
---|
759 | taking step of size 0.000710
|
---|
760 |
|
---|
761 | MBPT2: changing atomic coordinates:
|
---|
762 | Molecular formula: H2O
|
---|
763 | molecule<Molecule>: (
|
---|
764 | symmetry = c2v
|
---|
765 | unit = "angstrom"
|
---|
766 | { n atoms geometry }={
|
---|
767 | 1 O [ -0.0000000000 0.0000000000 0.3955783485]
|
---|
768 | 2 H [ 0.7643523982 0.0000000000 -0.1977891742]
|
---|
769 | 3 H [ -0.7643523982 -0.0000000000 -0.1977891742]
|
---|
770 | }
|
---|
771 | )
|
---|
772 | Atomic Masses:
|
---|
773 | 15.99491 1.00783 1.00783
|
---|
774 | Using symmetric orthogonalization.
|
---|
775 | n(SO): 10 1 5 3
|
---|
776 | Maximum orthogonalization residual = 4.65247
|
---|
777 | Minimum orthogonalization residual = 0.0226703
|
---|
778 |
|
---|
779 | Entered memgrp based MP2 routine
|
---|
780 | nproc = 1
|
---|
781 | Memory available per node: 32000000 Bytes
|
---|
782 | Static memory used per node: 9584 Bytes
|
---|
783 | Total memory used per node: 133376 Bytes
|
---|
784 | Memory required for one pass: 133376 Bytes
|
---|
785 | Minimum memory required: 56768 Bytes
|
---|
786 | Batch size: 4
|
---|
787 | npass rest nbasis nshell nfuncmax
|
---|
788 | 1 0 19 8 6
|
---|
789 | nocc nvir nfzc nfzv
|
---|
790 | 5 14 1 1
|
---|
791 |
|
---|
792 | SCF::compute: energy accuracy = 1.0000000e-08
|
---|
793 |
|
---|
794 | integral intermediate storage = 236328 bytes
|
---|
795 | integral cache = 31760632 bytes
|
---|
796 | nuclear repulsion energy = 9.0961813790
|
---|
797 |
|
---|
798 | Using symmetric orthogonalization.
|
---|
799 | n(SO): 10 1 5 3
|
---|
800 | Maximum orthogonalization residual = 4.65247
|
---|
801 | Minimum orthogonalization residual = 0.0226703
|
---|
802 | 19108 integrals
|
---|
803 | iter 1 energy = -76.0098983497 delta = 2.09985e-01
|
---|
804 | 19108 integrals
|
---|
805 | iter 2 energy = -76.0098984845 delta = 5.91205e-05
|
---|
806 | 19108 integrals
|
---|
807 | iter 3 energy = -76.0098984943 delta = 1.37979e-05
|
---|
808 | 19108 integrals
|
---|
809 | iter 4 energy = -76.0098984968 delta = 5.62552e-06
|
---|
810 | 19108 integrals
|
---|
811 | iter 5 energy = -76.0098984971 delta = 2.04290e-06
|
---|
812 | 19108 integrals
|
---|
813 | iter 6 energy = -76.0098984971 delta = 1.06788e-06
|
---|
814 | 19108 integrals
|
---|
815 | iter 7 energy = -76.0098984971 delta = 9.64846e-08
|
---|
816 | 19108 integrals
|
---|
817 | iter 8 energy = -76.0098984971 delta = 1.70482e-08
|
---|
818 |
|
---|
819 | HOMO is 1 B2 = -0.497269
|
---|
820 | LUMO is 4 A1 = 0.208461
|
---|
821 |
|
---|
822 | total scf energy = -76.0098984971
|
---|
823 |
|
---|
824 | Memory used for integral intermediates: 823288 Bytes
|
---|
825 | Memory used for integral storage: 15531252 Bytes
|
---|
826 | Size of global distributed array: 57760 Bytes
|
---|
827 | Beginning pass 1
|
---|
828 | Begin loop over shells (erep, 1.+2. q.t.)
|
---|
829 | working on shell pair ( 0 0), 5.6% complete
|
---|
830 | working on shell pair ( 1 1), 11.1% complete
|
---|
831 | working on shell pair ( 2 1), 16.7% complete
|
---|
832 | working on shell pair ( 3 0), 22.2% complete
|
---|
833 | working on shell pair ( 3 2), 27.8% complete
|
---|
834 | working on shell pair ( 4 0), 33.3% complete
|
---|
835 | working on shell pair ( 4 2), 38.9% complete
|
---|
836 | working on shell pair ( 4 4), 44.4% complete
|
---|
837 | working on shell pair ( 5 1), 50.0% complete
|
---|
838 | working on shell pair ( 5 3), 55.6% complete
|
---|
839 | working on shell pair ( 5 5), 61.1% complete
|
---|
840 | working on shell pair ( 6 1), 66.7% complete
|
---|
841 | working on shell pair ( 6 3), 72.2% complete
|
---|
842 | working on shell pair ( 6 5), 77.8% complete
|
---|
843 | working on shell pair ( 7 0), 83.3% complete
|
---|
844 | working on shell pair ( 7 2), 88.9% complete
|
---|
845 | working on shell pair ( 7 4), 94.4% complete
|
---|
846 | working on shell pair ( 7 6), 100.0% complete
|
---|
847 | End of loop over shells
|
---|
848 | Begin third q.t.
|
---|
849 | End of third q.t.
|
---|
850 | Begin fourth q.t.
|
---|
851 | End of fourth q.t.
|
---|
852 | Begin third and fourth q.b.t.
|
---|
853 | working on shell pair ( 0 0), 5.6% complete
|
---|
854 | working on shell pair ( 1 1), 11.1% complete
|
---|
855 | working on shell pair ( 2 1), 16.7% complete
|
---|
856 | working on shell pair ( 3 0), 22.2% complete
|
---|
857 | working on shell pair ( 3 2), 27.8% complete
|
---|
858 | working on shell pair ( 4 0), 33.3% complete
|
---|
859 | working on shell pair ( 4 2), 38.9% complete
|
---|
860 | working on shell pair ( 4 4), 44.4% complete
|
---|
861 | working on shell pair ( 5 1), 50.0% complete
|
---|
862 | working on shell pair ( 5 3), 55.6% complete
|
---|
863 | working on shell pair ( 5 5), 61.1% complete
|
---|
864 | working on shell pair ( 6 1), 66.7% complete
|
---|
865 | working on shell pair ( 6 3), 72.2% complete
|
---|
866 | working on shell pair ( 6 5), 77.8% complete
|
---|
867 | working on shell pair ( 7 0), 83.3% complete
|
---|
868 | working on shell pair ( 7 2), 88.9% complete
|
---|
869 | working on shell pair ( 7 4), 94.4% complete
|
---|
870 | working on shell pair ( 7 6), 100.0% complete
|
---|
871 | End of third and fourth q.b.t.
|
---|
872 | Done with pass 1
|
---|
873 |
|
---|
874 | Largest first order coefficients (unique):
|
---|
875 | 1 -0.04777200 1 B2 1 B2 -> 2 B2 2 B2 (+-+-)
|
---|
876 | 2 -0.03426863 1 B1 1 B1 -> 2 B1 2 B1 (+-+-)
|
---|
877 | 3 -0.03181833 3 A1 3 A1 -> 6 A1 6 A1 (+-+-)
|
---|
878 | 4 -0.02841278 1 B2 3 A1 -> 2 B2 6 A1 (+-+-)
|
---|
879 | 5 0.02679118 1 B2 1 B1 -> 2 B2 4 B1 (+-+-)
|
---|
880 | 6 -0.02656213 1 B1 1 B1 -> 4 B1 4 B1 (+-+-)
|
---|
881 | 7 0.02588958 1 B2 1 B1 -> 2 B2 2 B1 (+-+-)
|
---|
882 | 8 -0.02544631 1 B2 3 A1 -> 2 B2 6 A1 (++++)
|
---|
883 | 9 -0.02399412 1 B1 1 B1 -> 3 B1 3 B1 (+-+-)
|
---|
884 | 10 0.02329975 1 B2 1 B1 -> 2 B2 2 B1 (++++)
|
---|
885 |
|
---|
886 | RHF energy [au]: -76.009898497099
|
---|
887 | MP2 correlation energy [au]: -0.177231327463
|
---|
888 | MP2 energy [au]: -76.187129824562
|
---|
889 |
|
---|
890 | D1(MP2) = 0.00756887
|
---|
891 | S2 matrix 1-norm = 0.00794749
|
---|
892 | S2 matrix inf-norm = 0.01435192
|
---|
893 | S2 diagnostic = 0.00459115
|
---|
894 |
|
---|
895 | Largest S2 values (unique determinants):
|
---|
896 | 1 0.00566289 1 B2 -> 2 B2
|
---|
897 | 2 0.00527462 1 B1 -> 4 B1
|
---|
898 | 3 -0.00521941 3 A1 -> 4 A1
|
---|
899 | 4 -0.00441177 1 B1 -> 2 B1
|
---|
900 | 5 0.00338799 3 A1 -> 5 A1
|
---|
901 | 6 0.00328323 2 A1 -> 5 A1
|
---|
902 | 7 0.00309128 2 A1 -> 6 A1
|
---|
903 | 8 -0.00283989 1 B1 -> 5 B1
|
---|
904 | 9 0.00272808 2 A1 -> 4 A1
|
---|
905 | 10 0.00249606 3 A1 -> 7 A1
|
---|
906 |
|
---|
907 | D2(MP1) = 0.10644656
|
---|
908 |
|
---|
909 | CPHF: iter = 1 rms(P) = 0.0056206174 eps = 0.0000000100
|
---|
910 | CPHF: iter = 2 rms(P) = 0.0018117604 eps = 0.0000000100
|
---|
911 | CPHF: iter = 3 rms(P) = 0.0001948624 eps = 0.0000000100
|
---|
912 | CPHF: iter = 4 rms(P) = 0.0000247364 eps = 0.0000000100
|
---|
913 | CPHF: iter = 5 rms(P) = 0.0000053189 eps = 0.0000000100
|
---|
914 | CPHF: iter = 6 rms(P) = 0.0000005618 eps = 0.0000000100
|
---|
915 | CPHF: iter = 7 rms(P) = 0.0000000330 eps = 0.0000000100
|
---|
916 | CPHF: iter = 8 rms(P) = 0.0000000021 eps = 0.0000000100
|
---|
917 |
|
---|
918 | Total MP2 gradient [au]:
|
---|
919 | 1 O -0.0000000000 -0.0000000000 -0.0000200207
|
---|
920 | 2 H -0.0000027704 -0.0000000000 0.0000100103
|
---|
921 | 3 H 0.0000027704 0.0000000000 0.0000100103
|
---|
922 |
|
---|
923 | Max Gradient : 0.0000200207 0.0001000000 yes
|
---|
924 | Max Displacement : 0.0000434010 0.0001000000 yes
|
---|
925 | Gradient*Displace: 0.0000000012 0.0001000000 yes
|
---|
926 |
|
---|
927 | All convergence criteria have been met.
|
---|
928 | The optimization has converged.
|
---|
929 |
|
---|
930 | Value of the MolecularEnergy: -76.1871298246
|
---|
931 |
|
---|
932 | MBPT2:
|
---|
933 | Function Parameters:
|
---|
934 | value_accuracy = 2.081394e-07 (1.000000e-06) (computed)
|
---|
935 | gradient_accuracy = 0.000000e+00 (2.511201e-07) (computed)
|
---|
936 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
|
---|
937 |
|
---|
938 | Molecular Coordinates:
|
---|
939 | IntMolecularCoor Parameters:
|
---|
940 | update_bmat = no
|
---|
941 | scale_bonds = 1
|
---|
942 | scale_bends = 1
|
---|
943 | scale_tors = 1
|
---|
944 | scale_outs = 1
|
---|
945 | symmetry_tolerance = 1.000000e-05
|
---|
946 | simple_tolerance = 1.000000e-03
|
---|
947 | coordinate_tolerance = 1.000000e-07
|
---|
948 | have_fixed_values = 0
|
---|
949 | max_update_steps = 100
|
---|
950 | max_update_disp = 0.500000
|
---|
951 | have_fixed_values = 0
|
---|
952 |
|
---|
953 | Molecular formula: H2O
|
---|
954 | molecule<Molecule>: (
|
---|
955 | symmetry = c2v
|
---|
956 | unit = "angstrom"
|
---|
957 | { n atoms geometry }={
|
---|
958 | 1 O [ -0.0000000000 0.0000000000 0.3955783485]
|
---|
959 | 2 H [ 0.7643523982 0.0000000000 -0.1977891742]
|
---|
960 | 3 H [ -0.7643523982 -0.0000000000 -0.1977891742]
|
---|
961 | }
|
---|
962 | )
|
---|
963 | Atomic Masses:
|
---|
964 | 15.99491 1.00783 1.00783
|
---|
965 |
|
---|
966 | Bonds:
|
---|
967 | STRE s1 0.96764 1 2 O-H
|
---|
968 | STRE s2 0.96764 1 3 O-H
|
---|
969 | Bends:
|
---|
970 | BEND b1 104.35555 2 1 3 H-O-H
|
---|
971 |
|
---|
972 | SymmMolecularCoor Parameters:
|
---|
973 | change_coordinates = no
|
---|
974 | transform_hessian = yes
|
---|
975 | max_kappa2 = 10.000000
|
---|
976 |
|
---|
977 | GaussianBasisSet:
|
---|
978 | nbasis = 19
|
---|
979 | nshell = 8
|
---|
980 | nprim = 19
|
---|
981 | name = "6-31G*"
|
---|
982 | Reference Wavefunction:
|
---|
983 | Function Parameters:
|
---|
984 | value_accuracy = 2.081394e-09 (1.000000e-08) (computed)
|
---|
985 | gradient_accuracy = 0.000000e+00 (1.000000e-06)
|
---|
986 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
|
---|
987 |
|
---|
988 | Molecule:
|
---|
989 | Molecular formula: H2O
|
---|
990 | molecule<Molecule>: (
|
---|
991 | symmetry = c2v
|
---|
992 | unit = "angstrom"
|
---|
993 | { n atoms geometry }={
|
---|
994 | 1 O [ -0.0000000000 0.0000000000 0.3955783485]
|
---|
995 | 2 H [ 0.7643523982 0.0000000000 -0.1977891742]
|
---|
996 | 3 H [ -0.7643523982 -0.0000000000 -0.1977891742]
|
---|
997 | }
|
---|
998 | )
|
---|
999 | Atomic Masses:
|
---|
1000 | 15.99491 1.00783 1.00783
|
---|
1001 |
|
---|
1002 | GaussianBasisSet:
|
---|
1003 | nbasis = 19
|
---|
1004 | nshell = 8
|
---|
1005 | nprim = 19
|
---|
1006 | name = "6-31G*"
|
---|
1007 | SCF Parameters:
|
---|
1008 | maxiter = 40
|
---|
1009 | density_reset_frequency = 10
|
---|
1010 | level_shift = 0.000000
|
---|
1011 |
|
---|
1012 | CLSCF Parameters:
|
---|
1013 | charge = 0
|
---|
1014 | ndocc = 5
|
---|
1015 | docc = [ 3 0 1 1 ]
|
---|
1016 |
|
---|
1017 |
|
---|
1018 | The following keywords in "h2omp2_mp211631gsc2vopt.in" were ignored:
|
---|
1019 | mpqc:mole:reference:guess_wavefunction:multiplicity
|
---|
1020 | mpqc:mole:reference:multiplicity
|
---|
1021 |
|
---|
1022 | CPU Wall
|
---|
1023 | mpqc: 2.60 2.75
|
---|
1024 | calc: 2.40 2.56
|
---|
1025 | mp2-mem: 2.36 2.51
|
---|
1026 | Laj: 0.13 0.14
|
---|
1027 | make_gmat for Laj: 0.11 0.11
|
---|
1028 | gmat: 0.11 0.11
|
---|
1029 | Pab and Wab: 0.00 0.00
|
---|
1030 | Pkj and Wkj: 0.05 0.05
|
---|
1031 | make_gmat for Wkj: 0.04 0.04
|
---|
1032 | gmat: 0.04 0.04
|
---|
1033 | cphf: 0.33 0.33
|
---|
1034 | gmat: 0.28 0.28
|
---|
1035 | hcore contrib.: 0.05 0.05
|
---|
1036 | mp2 passes: 0.50 0.58
|
---|
1037 | 1. q.b.t.: 0.00 0.00
|
---|
1038 | 2. q.b.t.: 0.01 0.00
|
---|
1039 | 3. q.t.: 0.01 0.01
|
---|
1040 | 3.qbt+4.qbt+non-sep contrib.: 0.22 0.28
|
---|
1041 | 4. q.t.: 0.00 0.00
|
---|
1042 | Pab and Wab: 0.01 0.01
|
---|
1043 | Pkj and Wkj: 0.00 0.00
|
---|
1044 | Waj and Laj: 0.00 0.00
|
---|
1045 | compute ecorr: 0.00 0.00
|
---|
1046 | divide (ia|jb)'s: 0.01 0.00
|
---|
1047 | erep+1.qt+2.qt: 0.24 0.26
|
---|
1048 | overlap contrib.: 0.02 0.01
|
---|
1049 | sep 2PDM contrib.: 0.17 0.22
|
---|
1050 | vector: 0.66 0.68
|
---|
1051 | density: 0.01 0.02
|
---|
1052 | evals: 0.01 0.04
|
---|
1053 | extrap: 0.06 0.06
|
---|
1054 | fock: 0.44 0.44
|
---|
1055 | accum: 0.00 0.00
|
---|
1056 | ao_gmat: 0.10 0.15
|
---|
1057 | start thread: 0.10 0.13
|
---|
1058 | stop thread: 0.00 0.01
|
---|
1059 | init pmax: 0.00 0.00
|
---|
1060 | local data: 0.00 0.01
|
---|
1061 | setup: 0.09 0.12
|
---|
1062 | sum: 0.00 0.00
|
---|
1063 | symm: 0.24 0.14
|
---|
1064 | input: 0.20 0.19
|
---|
1065 | vector: 0.05 0.04
|
---|
1066 | density: 0.00 0.00
|
---|
1067 | evals: 0.00 0.00
|
---|
1068 | extrap: 0.01 0.01
|
---|
1069 | fock: 0.02 0.02
|
---|
1070 | accum: 0.00 0.00
|
---|
1071 | ao_gmat: 0.01 0.01
|
---|
1072 | start thread: 0.01 0.00
|
---|
1073 | stop thread: 0.00 0.00
|
---|
1074 | init pmax: 0.00 0.00
|
---|
1075 | local data: 0.00 0.00
|
---|
1076 | setup: 0.01 0.01
|
---|
1077 | sum: 0.00 0.00
|
---|
1078 | symm: 0.00 0.01
|
---|
1079 |
|
---|
1080 | End Time: Sat Apr 6 13:36:00 2002
|
---|
1081 |
|
---|