1 |
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2 | MPQC: Massively Parallel Quantum Chemistry
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3 | Version 2.1.0-alpha-gcc3
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4 |
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5 | Machine: i686-pc-linux-gnu
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6 | User: cljanss@aros.ca.sandia.gov
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7 | Start Time: Sat Apr 6 13:34:24 2002
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8 |
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9 | Using ProcMessageGrp for message passing (number of nodes = 1).
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10 | Using PthreadThreadGrp for threading (number of threads = 2).
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11 | Using ProcMemoryGrp for distributed shared memory.
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12 | Total number of processors = 2
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13 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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14 |
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15 | IntCoorGen: generated 3 coordinates.
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16 | Forming optimization coordinates:
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17 | SymmMolecularCoor::form_variable_coordinates()
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18 | expected 3 coordinates
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19 | found 2 variable coordinates
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20 | found 0 constant coordinates
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21 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
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22 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
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23 |
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24 | CLSCF::init: total charge = 0
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25 |
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26 | docc = [ 5 ]
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27 | nbasis = 7
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28 |
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29 | CLSCF::init: total charge = 0
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30 |
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31 | docc = [ 5 ]
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32 | nbasis = 7
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33 |
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34 | Molecular formula H2O
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35 |
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36 | MPQC options:
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37 | matrixkit = <ReplSCMatrixKit>
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38 | filename = h2o_scfsto3gc1
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39 | restart_file = h2o_scfsto3gc1.ckpt
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40 | restart = no
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41 | checkpoint = no
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42 | savestate = no
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43 | do_energy = yes
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44 | do_gradient = no
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45 | optimize = no
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46 | write_pdb = no
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47 | print_mole = yes
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48 | print_timings = yes
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49 |
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50 | SCF::compute: energy accuracy = 1.0000000e-06
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51 |
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52 | integral intermediate storage = 31876 bytes
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53 | integral cache = 31967676 bytes
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54 | Using symmetric orthogonalization.
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55 | n(SO): 7
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56 | Maximum orthogonalization residual = 1.9104
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57 | Minimum orthogonalization residual = 0.344888
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58 | Using symmetric orthogonalization.
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59 | n(SO): 7
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60 | Maximum orthogonalization residual = 1.9104
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61 | Minimum orthogonalization residual = 0.344888
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62 | Using guess wavefunction as starting vector
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63 |
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64 | SCF::compute: energy accuracy = 1.0000000e-06
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65 |
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66 | integral intermediate storage = 31876 bytes
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67 | integral cache = 31967676 bytes
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68 | Starting from core Hamiltonian guess
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69 |
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70 | nuclear repulsion energy = 9.1571164588
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71 |
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72 | 733 integrals
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73 | iter 1 energy = -74.6468200575 delta = 7.47196e-01
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74 | 733 integrals
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75 | iter 2 energy = -74.9403205745 delta = 2.23216e-01
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76 | 733 integrals
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77 | iter 3 energy = -74.9595428818 delta = 6.69340e-02
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78 | 733 integrals
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79 | iter 4 energy = -74.9606520926 delta = 2.02576e-02
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80 | 733 integrals
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81 | iter 5 energy = -74.9607020706 delta = 4.09811e-03
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82 | 733 integrals
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83 | iter 6 energy = -74.9607024821 delta = 3.66040e-04
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84 | 733 integrals
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85 | iter 7 energy = -74.9607024827 delta = 1.47732e-05
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86 |
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87 | HOMO is 5 A = -0.386942
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88 | LUMO is 6 A = 0.592900
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89 |
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90 | total scf energy = -74.9607024827
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91 |
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92 | nuclear repulsion energy = 9.1571164588
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93 |
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94 | 733 integrals
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95 | iter 1 energy = -74.9607024827 delta = 7.72168e-01
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96 | 733 integrals
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97 | iter 2 energy = -74.9607024827 delta = 6.14966e-10
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98 |
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99 | HOMO is 5 A = -0.386942
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100 | LUMO is 6 A = 0.592900
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101 |
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102 | total scf energy = -74.9607024827
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103 |
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104 | Value of the MolecularEnergy: -74.9607024827
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105 |
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106 | Function Parameters:
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107 | value_accuracy = 9.286122e-11 (1.000000e-06) (computed)
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108 | gradient_accuracy = 0.000000e+00 (1.000000e-06)
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109 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
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110 |
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111 | Molecular Coordinates:
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112 | IntMolecularCoor Parameters:
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113 | update_bmat = no
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114 | scale_bonds = 1
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115 | scale_bends = 1
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116 | scale_tors = 1
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117 | scale_outs = 1
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118 | symmetry_tolerance = 1.000000e-05
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119 | simple_tolerance = 1.000000e-03
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120 | coordinate_tolerance = 1.000000e-07
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121 | have_fixed_values = 0
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122 | max_update_steps = 100
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123 | max_update_disp = 0.500000
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124 | have_fixed_values = 0
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125 |
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126 | Molecular formula: H2O
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127 | molecule<Molecule>: (
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128 | symmetry = c1
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129 | unit = "angstrom"
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130 | { n atoms geometry }={
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131 | 1 O [ 0.0000000000 0.0000000000 0.3693729440]
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132 | 2 H [ 0.7839758990 0.0000000000 -0.1846864720]
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133 | 3 H [ -0.7839758990 0.0000000000 -0.1846864720]
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134 | }
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135 | )
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136 | Atomic Masses:
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137 | 15.99491 1.00783 1.00783
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138 |
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139 | Bonds:
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140 | STRE s1 0.96000 1 2 O-H
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141 | STRE s2 0.96000 1 3 O-H
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142 | Bends:
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143 | BEND b1 109.50000 2 1 3 H-O-H
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144 |
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145 | SymmMolecularCoor Parameters:
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146 | change_coordinates = no
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147 | transform_hessian = yes
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148 | max_kappa2 = 10.000000
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149 |
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150 | GaussianBasisSet:
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151 | nbasis = 7
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152 | nshell = 4
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153 | nprim = 12
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154 | name = "STO-3G"
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155 | Natural Population Analysis:
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156 | n atom charge ne(S) ne(P)
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157 | 1 O -0.404502 3.732558 4.671944
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158 | 2 H 0.202251 0.797749
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159 | 3 H 0.202251 0.797749
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160 |
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161 | SCF Parameters:
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162 | maxiter = 40
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163 | density_reset_frequency = 10
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164 | level_shift = 0.000000
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165 |
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166 | CLSCF Parameters:
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167 | charge = 0
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168 | ndocc = 5
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169 | docc = [ 5 ]
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170 |
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171 | The following keywords in "h2o_scfsto3gc1.in" were ignored:
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172 | mpqc:mole:guess_wavefunction:multiplicity
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173 | mpqc:mole:multiplicity
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174 |
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175 | CPU Wall
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176 | mpqc: 0.16 0.17
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177 | NAO: 0.00 0.00
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178 | calc: 0.03 0.04
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179 | vector: 0.03 0.04
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180 | density: 0.00 0.00
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181 | evals: 0.00 0.00
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182 | extrap: 0.00 0.00
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183 | fock: 0.00 0.00
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184 | accum: 0.00 0.00
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185 | ao_gmat: 0.00 0.00
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186 | start thread: 0.00 0.00
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187 | stop thread: 0.00 0.00
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188 | init pmax: 0.00 0.00
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189 | local data: 0.00 0.00
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190 | setup: 0.00 0.00
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191 | sum: 0.00 0.00
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192 | symm: 0.00 0.00
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193 | vector: 0.02 0.02
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194 | density: 0.00 0.00
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195 | evals: 0.00 0.00
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196 | extrap: 0.01 0.00
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197 | fock: 0.00 0.01
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198 | accum: 0.00 0.00
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199 | ao_gmat: 0.00 0.01
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200 | start thread: 0.00 0.00
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201 | stop thread: 0.00 0.00
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202 | init pmax: 0.00 0.00
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203 | local data: 0.00 0.00
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204 | setup: 0.00 0.00
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205 | sum: 0.00 0.00
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206 | symm: 0.00 0.00
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207 | input: 0.12 0.13
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208 |
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209 | End Time: Sat Apr 6 13:34:25 2002
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210 |
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