1 |
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2 | MPQC: Massively Parallel Quantum Chemistry
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3 | Version 2.1.0-alpha-gcc3
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4 |
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5 | Machine: i686-pc-linux-gnu
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6 | User: cljanss@aros.ca.sandia.gov
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7 | Start Time: Sat Apr 6 13:33:49 2002
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8 |
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9 | Using ProcMessageGrp for message passing (number of nodes = 1).
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10 | Using PthreadThreadGrp for threading (number of threads = 2).
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11 | Using ProcMemoryGrp for distributed shared memory.
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12 | Total number of processors = 2
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13 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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14 |
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15 | IntCoorGen: generated 3 coordinates.
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16 | Forming optimization coordinates:
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17 | SymmMolecularCoor::form_variable_coordinates()
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18 | expected 3 coordinates
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19 | found 2 variable coordinates
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20 | found 0 constant coordinates
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21 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/6-311gSS.kv.
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22 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
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23 |
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24 | CLSCF::init: total charge = 0
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25 |
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26 | docc = [ 5 ]
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27 | nbasis = 7
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28 |
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29 | CLSCF::init: total charge = 0
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30 |
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31 | docc = [ 5 ]
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32 | nbasis = 30
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33 | Using symmetric orthogonalization.
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34 | n(SO): 30
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35 | Maximum orthogonalization residual = 4.46641
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36 | Minimum orthogonalization residual = 0.0188915
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37 |
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38 | Molecular formula H2O
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39 |
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40 | MPQC options:
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41 | matrixkit = <ReplSCMatrixKit>
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42 | filename = h2o_mp2006311gssc1
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43 | restart_file = h2o_mp2006311gssc1.ckpt
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44 | restart = no
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45 | checkpoint = no
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46 | savestate = no
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47 | do_energy = yes
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48 | do_gradient = no
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49 | optimize = no
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50 | write_pdb = no
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51 | print_mole = yes
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52 | print_timings = yes
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53 |
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54 | Entered memgrp based MP2 routine
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55 | nproc = 1
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56 | Memory available per node: 32000000 Bytes
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57 | Static memory used per node: 9600 Bytes
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58 | Total memory used per node: 262000 Bytes
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59 | Memory required for one pass: 262000 Bytes
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60 | Minimum memory required: 69040 Bytes
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61 | Batch size: 5
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62 | npass rest nbasis nshell nfuncmax
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63 | 1 0 30 13 5
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64 | nocc nvir nfzc nfzv
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65 | 5 25 0 0
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66 |
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67 | SCF::compute: energy accuracy = 1.0000000e-08
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68 |
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69 | integral intermediate storage = 260598 bytes
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70 | integral cache = 31731962 bytes
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71 | Projecting guess wavefunction into the present basis set
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72 |
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73 | SCF::compute: energy accuracy = 1.0000000e-06
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74 |
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75 | integral intermediate storage = 31876 bytes
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76 | integral cache = 31967676 bytes
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77 | Starting from core Hamiltonian guess
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78 |
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79 | Using symmetric orthogonalization.
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80 | n(SO): 7
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81 | Maximum orthogonalization residual = 1.9104
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82 | Minimum orthogonalization residual = 0.344888
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83 | nuclear repulsion energy = 9.1571164588
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84 |
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85 | 733 integrals
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86 | iter 1 energy = -74.6468200575 delta = 7.47196e-01
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87 | 733 integrals
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88 | iter 2 energy = -74.9403205745 delta = 2.23216e-01
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89 | 733 integrals
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90 | iter 3 energy = -74.9595428818 delta = 6.69340e-02
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91 | 733 integrals
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92 | iter 4 energy = -74.9606520926 delta = 2.02576e-02
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93 | 733 integrals
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94 | iter 5 energy = -74.9607020706 delta = 4.09811e-03
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95 | 733 integrals
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96 | iter 6 energy = -74.9607024821 delta = 3.66040e-04
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97 | 733 integrals
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98 | iter 7 energy = -74.9607024827 delta = 1.47732e-05
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99 |
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100 | HOMO is 5 A = -0.386942
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101 | LUMO is 6 A = 0.592900
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102 |
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103 | total scf energy = -74.9607024827
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104 |
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105 | Projecting the guess density.
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106 |
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107 | The number of electrons in the guess density = 10
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108 | The number of electrons in the projected density = 9.99139
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109 |
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110 | nuclear repulsion energy = 9.1571164588
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111 |
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112 | 127194 integrals
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113 | iter 1 energy = -75.7283928106 delta = 9.87360e-02
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114 | 127292 integrals
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115 | iter 2 energy = -76.0314750633 delta = 3.60005e-02
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116 | 127291 integrals
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117 | iter 3 energy = -76.0437203673 delta = 6.49018e-03
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118 | 127292 integrals
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119 | iter 4 energy = -76.0452918417 delta = 2.49056e-03
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120 | 127291 integrals
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121 | iter 5 energy = -76.0456219144 delta = 9.38963e-04
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122 | 127291 integrals
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123 | iter 6 energy = -76.0456765911 delta = 5.91379e-04
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124 | 127292 integrals
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125 | iter 7 energy = -76.0456769437 delta = 3.76481e-05
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126 | 127292 integrals
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127 | iter 8 energy = -76.0456769851 delta = 1.26111e-05
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128 | 127291 integrals
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129 | iter 9 energy = -76.0456769889 delta = 3.98043e-06
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130 | 127292 integrals
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131 | iter 10 energy = -76.0456769891 delta = 9.59448e-07
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132 | 127291 integrals
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133 | iter 11 energy = -76.0456769891 delta = 1.56483e-07
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134 | 127292 integrals
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135 | iter 12 energy = -76.0456769891 delta = 3.11107e-08
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136 |
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137 | HOMO is 5 A = -0.497601
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138 | LUMO is 6 A = 0.150997
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139 |
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140 | total scf energy = -76.0456769891
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141 |
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142 | Memory used for integral intermediates: 260598 Bytes
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143 | Memory used for integral storage: 15748301 Bytes
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144 | Size of global distributed array: 180000 Bytes
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145 | Beginning pass 1
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146 | Begin loop over shells (erep, 1.+2. q.t.)
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147 | working on shell pair ( 0 0), 2.2% complete
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148 | working on shell pair ( 3 2), 11.1% complete
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149 | working on shell pair ( 5 1), 20.0% complete
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150 | working on shell pair ( 6 3), 28.9% complete
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151 | working on shell pair ( 7 4), 37.8% complete
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152 | working on shell pair ( 8 4), 46.7% complete
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153 | working on shell pair ( 9 3), 55.6% complete
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154 | working on shell pair ( 10 1), 64.4% complete
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155 | working on shell pair ( 10 9), 73.3% complete
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156 | working on shell pair ( 11 6), 82.2% complete
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157 | working on shell pair ( 12 2), 91.1% complete
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158 | working on shell pair ( 12 10), 100.0% complete
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159 | End of loop over shells
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160 | Begin third q.t.
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161 | End of third q.t.
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162 | Begin fourth q.t.
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163 | End of fourth q.t.
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164 |
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165 | Largest first order coefficients (unique):
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166 | 1 -0.04510001 5 A 5 A -> 11 A 11 A (+-+-)
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167 | 2 -0.03742631 4 A 4 A -> 10 A 10 A (+-+-)
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168 | 3 -0.03122608 5 A 4 A -> 11 A 10 A (+-+-)
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169 | 4 -0.02685570 3 A 3 A -> 8 A 8 A (+-+-)
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170 | 5 -0.02629418 5 A 4 A -> 11 A 10 A (++++)
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171 | 6 0.02441203 5 A 3 A -> 11 A 12 A (+-+-)
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172 | 7 -0.02404366 3 A 3 A -> 12 A 12 A (+-+-)
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173 | 8 -0.02272080 3 A 3 A -> 9 A 9 A (+-+-)
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174 | 9 -0.02189394 4 A 4 A -> 8 A 8 A (+-+-)
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175 | 10 0.02150831 4 A 3 A -> 10 A 12 A (+-+-)
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176 |
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177 | RHF energy [au]: -76.045676989113
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178 | MP2 correlation energy [au]: -0.235997495436
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179 | MP2 energy [au]: -76.281674484549
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180 |
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181 | Value of the MolecularEnergy: -76.2816744845
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182 |
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183 | MBPT2:
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184 | Function Parameters:
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185 | value_accuracy = 9.361855e-07 (1.000000e-06) (computed)
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186 | gradient_accuracy = 0.000000e+00 (1.000000e-06)
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187 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
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188 |
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189 | Molecular Coordinates:
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190 | IntMolecularCoor Parameters:
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191 | update_bmat = no
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192 | scale_bonds = 1
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193 | scale_bends = 1
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194 | scale_tors = 1
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195 | scale_outs = 1
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196 | symmetry_tolerance = 1.000000e-05
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197 | simple_tolerance = 1.000000e-03
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198 | coordinate_tolerance = 1.000000e-07
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199 | have_fixed_values = 0
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200 | max_update_steps = 100
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201 | max_update_disp = 0.500000
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202 | have_fixed_values = 0
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203 |
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204 | Molecular formula: H2O
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205 | molecule<Molecule>: (
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206 | symmetry = c1
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207 | unit = "angstrom"
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208 | { n atoms geometry }={
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209 | 1 O [ 0.0000000000 0.0000000000 0.3693729440]
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210 | 2 H [ 0.7839758990 0.0000000000 -0.1846864720]
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211 | 3 H [ -0.7839758990 0.0000000000 -0.1846864720]
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212 | }
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213 | )
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214 | Atomic Masses:
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215 | 15.99491 1.00783 1.00783
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216 |
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217 | Bonds:
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218 | STRE s1 0.96000 1 2 O-H
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219 | STRE s2 0.96000 1 3 O-H
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220 | Bends:
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221 | BEND b1 109.50000 2 1 3 H-O-H
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222 |
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223 | SymmMolecularCoor Parameters:
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224 | change_coordinates = no
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225 | transform_hessian = yes
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226 | max_kappa2 = 10.000000
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227 |
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228 | GaussianBasisSet:
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229 | nbasis = 30
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230 | nshell = 13
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231 | nprim = 24
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232 | name = "6-311G**"
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233 | Reference Wavefunction:
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234 | Function Parameters:
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235 | value_accuracy = 9.361855e-09 (1.000000e-08) (computed)
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236 | gradient_accuracy = 0.000000e+00 (1.000000e-06)
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237 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
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238 |
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239 | Molecule:
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240 | Molecular formula: H2O
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241 | molecule<Molecule>: (
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242 | symmetry = c1
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243 | unit = "angstrom"
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244 | { n atoms geometry }={
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245 | 1 O [ 0.0000000000 0.0000000000 0.3693729440]
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246 | 2 H [ 0.7839758990 0.0000000000 -0.1846864720]
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247 | 3 H [ -0.7839758990 0.0000000000 -0.1846864720]
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248 | }
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249 | )
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250 | Atomic Masses:
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251 | 15.99491 1.00783 1.00783
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252 |
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253 | GaussianBasisSet:
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254 | nbasis = 30
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255 | nshell = 13
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256 | nprim = 24
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257 | name = "6-311G**"
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258 | SCF Parameters:
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259 | maxiter = 40
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260 | density_reset_frequency = 10
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261 | level_shift = 0.000000
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262 |
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263 | CLSCF Parameters:
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264 | charge = 0
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265 | ndocc = 5
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266 | docc = [ 5 ]
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267 |
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268 |
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269 | The following keywords in "h2o_mp2006311gssc1.in" were ignored:
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270 | mpqc:mole:reference:guess_wavefunction:multiplicity
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271 | mpqc:mole:reference:multiplicity
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272 |
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273 | CPU Wall
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274 | mpqc: 0.67 0.71
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275 | calc: 0.53 0.57
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276 | mp2-mem: 0.53 0.57
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277 | mp2 passes: 0.20 0.20
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278 | 3. q.t.: 0.01 0.01
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279 | 4. q.t.: 0.00 0.00
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280 | compute ecorr: 0.01 0.00
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281 | divide (ia|jb)'s: 0.00 0.00
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282 | erep+1.qt+2.qt: 0.18 0.18
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283 | vector: 0.31 0.35
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284 | density: 0.00 0.00
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285 | evals: 0.03 0.02
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286 | extrap: 0.03 0.02
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287 | fock: 0.20 0.24
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288 | accum: 0.00 0.00
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289 | ao_gmat: 0.20 0.23
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290 | start thread: 0.20 0.20
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291 | stop thread: 0.00 0.02
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292 | init pmax: 0.00 0.00
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293 | local data: 0.00 0.00
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294 | setup: 0.00 0.00
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295 | sum: 0.00 0.00
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296 | symm: 0.00 0.00
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297 | vector: 0.03 0.02
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298 | density: 0.00 0.00
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299 | evals: 0.00 0.00
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300 | extrap: 0.00 0.00
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301 | fock: 0.02 0.01
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302 | accum: 0.00 0.00
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303 | ao_gmat: 0.01 0.01
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304 | start thread: 0.01 0.00
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305 | stop thread: 0.00 0.00
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306 | init pmax: 0.00 0.00
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307 | local data: 0.00 0.00
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308 | setup: 0.00 0.00
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309 | sum: 0.00 0.00
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310 | symm: 0.00 0.00
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311 | input: 0.14 0.14
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312 |
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313 | End Time: Sat Apr 6 13:33:50 2002
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314 |
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